| Year |
Citation |
Score |
| 2021 |
Allred TK, Shaghafi MB, Chen PP, Tran Q, Houk KN, Overman LE. Constructing Saturated Guanidinum Heterocycles by Cycloaddition of -Amidinyliminium Ions with Indoles. Organic Letters. PMID 34546759 DOI: 10.1021/acs.orglett.1c02832 |
0.797 |
|
| 2020 |
Allred TK, Dieskau AP, Zhao P, Lackner GL, Overman LE. General Access to Concave-Substituted -Dioxabicyclo[3.3.0]octanones: Enantioselective Total Syntheses of Macfarlandin C and Dendrillolide A. The Journal of Organic Chemistry. PMID 33197184 DOI: 10.1021/acs.joc.0c02273 |
0.357 |
|
| 2020 |
Overman LE, Allred TK, Dieskau AP, Zhao P, Lackner GL. Enantioselective Total Synthesis of Macfarlandin C, a Spongian Diterpenoid Harboring a Concave-Substituted cis-Dioxabicyclo[3.3.0]octanone Fragment. Angewandte Chemie (International Ed. in English). PMID 31965671 DOI: 10.1002/Anie.201916753 |
0.47 |
|
| 2019 |
Overman LE, Weires NA, Slutskyy Y. Facile Preparation of Spirolactones by an Alkoxycarbonyl Radical Cyclization Cross-Coupling Cascade. Angewandte Chemie (International Ed. in English). PMID 30989757 DOI: 10.1002/Anie.201903353 |
0.818 |
|
| 2019 |
Pitre SP, Muuronen M, Fishman DA, Overman LE. Tertiary Alcohols as Radical Precursors for the Introduction of Tertiary Substituents into Heteroarenes Acs Catalysis. 9: 3413-3418. DOI: 10.1021/Acscatal.9B00405 |
0.434 |
|
| 2018 |
Kearney SE, Zahoránszky-Kőhalmi G, Brimacombe KR, Henderson MJ, Lynch C, Zhao T, Wan KK, Itkin Z, Dillon C, Shen M, Cheff DM, Lee TD, Bougie D, Cheng K, Coussens NP, ... ... Overman LE, et al. Canvass: A Crowd-Sourced, Natural-Product Screening Library for Exploring Biological Space. Acs Central Science. 4: 1727-1741. PMID 30648156 DOI: 10.1021/Acscentsci.8B00747 |
0.769 |
|
| 2018 |
Tao DJ, Slutskyy Y, Muuronen M, Le A, Kohler P, Overman LE. Correction to "Total Synthesis of (-)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade". Journal of the American Chemical Society. PMID 30582805 DOI: 10.1021/Jacs.8B13203 |
0.369 |
|
| 2018 |
Overman LE, Pitre SP, Weires NA. Forging C(sp3)-C(sp3) Bonds with Carbon-Centered Radicals in the Synthesis of Complex Molecules. Journal of the American Chemical Society. PMID 30566838 DOI: 10.1021/Jacs.8B11790 |
0.818 |
|
| 2018 |
Becker MH, Chua P, Downham R, Douglas CJ, Garg NK, Hiebert S, Jaroch S, Matsuoka RT, Middleton JA, Ng FW, Overman LE. Correction to "Total Synthesis of (-)-Sarain A". Journal of the American Chemical Society. PMID 29620879 DOI: 10.1021/Jacs.8B03357 |
0.699 |
|
| 2018 |
Tao D, Slutskyy Y, Muuronen M, Le A, Kohler P, Overman LE. Total Synthesis of (-)-Chromodorolide B By a Computationally-Guided Radical Addition/Cyclization/Fragmentation Cascade. Journal of the American Chemical Society. PMID 29412658 DOI: 10.1021/Jacs.7B13799 |
0.488 |
|
| 2018 |
Abbas SY, Zhao P, Overman LE. 1,6-Addition of Tertiary Carbon Radicals Generated From Alcohols or Carboxylic Acids by Visible-Light Photoredox Catalysis. Organic Letters. PMID 29360373 DOI: 10.1021/Acs.Orglett.7B04034 |
0.396 |
|
| 2018 |
Cannon JS, Overman LE. Discussion Addendum for: Preparation of the COP Catalysts: [( S )‐COP‐OAc] 2 , [( S )‐COP‐Cl] 2 , and ( S )‐COP‐hfacac Organic Syntheses. 95: 500-511. DOI: 10.1002/0471264229.Os095.33 |
0.63 |
|
| 2017 |
Garnsey MR, Slutskyy Y, Jamison CR, Zhao P, Lee J, Rhee YH, Overman LE. Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C via Convergent Fragment Coupling Using a Tertiary Carbon Radical. The Journal of Organic Chemistry. PMID 29130687 DOI: 10.1021/Acs.Joc.7B02458 |
0.831 |
|
| 2017 |
Slutskyy Y, Jamison CR, Zhao P, Lee J, Rhee YH, Overman LE. Versatile Construction of 6-Substituted cis-2,8-Dioxabicyclo[3.3.0]octan-3-ones. Short Enantioselective Total Syntheses of Cheloviolenes A and B and Dendrillolide C. Journal of the American Chemical Society. PMID 28514145 DOI: 10.1021/Jacs.7B04265 |
0.834 |
|
| 2017 |
Jamison CR, Slutskyy Y, Overman LE. Fragment Coupling and Formation of Quaternary Carbons by Visible‐Light Photoredox Catalyzed Reaction of tert‐Alkyl Hemioxalate Salts and Michael Acceptors Organic Syntheses. 94: 167-183. DOI: 10.1002/0471264229.Os094.13 |
0.431 |
|
| 2016 |
Cannon JS, Overman LE. Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts. Accounts of Chemical Research. PMID 27689745 DOI: 10.1021/Acs.Accounts.6B00398 |
0.731 |
|
| 2016 |
Martins LF, Mesquita JT, Pinto EG, Costa-Silva TA, Borborema SE, Galisteo Junior AJ, Neves BJ, Andrade CH, Shuhaib ZA, Bennett EL, Black GP, Harper PM, Evans DM, Fituri HS, Leyland JP, ... ... Overman LE, et al. Analogues of Marine Guanidine Alkaloids Are in Vitro Effective against Trypanosoma cruzi and Selectively Eliminate Leishmania (L.) infantum Intracellular Amastigotes. Journal of Natural Products. PMID 27586460 DOI: 10.1021/Acs.Jnatprod.6B00256 |
0.444 |
|
| 2016 |
Jamison CR, Overman LE. Fragment Coupling with Tertiary Radicals Generated by Visible-Light Photocatalysis. Accounts of Chemical Research. PMID 27491019 DOI: 10.1021/Acs.Accounts.6B00284 |
0.84 |
|
| 2016 |
Slutskyy Y, Jamison CR, Lackner GL, Müller DS, Dieskau AP, Unteidt NL, Overman LE. Short Enantioselective Total Syntheses of trans-Clerodane Diterpenoids: Convergent Fragment Coupling Using a trans-Decalin Tertiary Radical Generated from a Tertiary Alcohol Precursor. The Journal of Organic Chemistry. PMID 27254137 DOI: 10.1021/Acs.Joc.6B00697 |
0.848 |
|
| 2016 |
Slutskyy Y, Overman LE. Generation of the Methoxycarbonyl Radical by Visible-Light Photoredox Catalysis and Its Conjugate Addition with Electron-Deficient Olefins. Organic Letters. PMID 27186995 DOI: 10.1021/Acs.Orglett.6B00895 |
0.33 |
|
| 2016 |
Tao D, Muuronen M, Slutskyy Y, Le A, Furche F, Overman LE. Diastereoselective Coupling of Chiral Acetonide Trisubstituted Radicals with Alkenes. Chemistry (Weinheim An Der Bergstrasse, Germany). PMID 27128888 DOI: 10.1002/Chem.201601957 |
0.371 |
|
| 2016 |
Snigdha S, Prieto GA, Petrosyan A, Loertscher BM, Dieskau AP, Overman LE, Cotman CW. H3K9me3 Inhibition Improves Memory, Promotes Spine Formation, and Increases BDNF Levels in the Aged Hippocampus. The Journal of Neuroscience : the Official Journal of the Society For Neuroscience. 36: 3611-22. PMID 27013689 DOI: 10.1523/JNEUROSCI.2693-15.2016 |
0.754 |
|
| 2016 |
Tao DJ, Slutskyy Y, Overman LE. Total Synthesis of (-)-Chromodorolide B. Journal of the American Chemical Society. 138: 2186-9. PMID 26880210 DOI: 10.1021/Jacs.6B00541 |
0.459 |
|
| 2016 |
Büschleb M, Dorich S, Hanessian S, Tao D, Schenthal KB, Overman LE. Synthetic Strategies toward Natural Products Containing Contiguous Stereogenic Quaternary Carbon Atoms. Angewandte Chemie (International Ed. in English). PMID 26836448 DOI: 10.1002/Anie.201507549 |
0.385 |
|
| 2016 |
Nawrat CC, Jamison CR, Slutskyy Y, MacMillan DW, Overman LE. Correction to "Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling". Journal of the American Chemical Society. PMID 26820773 DOI: 10.1021/jacs.6b00456 |
0.785 |
|
| 2016 |
Cannon JS, Overman LE. ChemInform Abstract: Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts Cheminform. 47. DOI: 10.1002/chin.201650208 |
0.663 |
|
| 2016 |
Pratsch G, Overman LE. ChemInform Abstract: Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis. Cheminform. 47. DOI: 10.1002/chin.201614058 |
0.807 |
|
| 2016 |
Nawrat CC, Jamison CR, Slutskyy Y, MacMillan DWC, Overman LE. ChemInform Abstract: Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. Cheminform. 47: no-no. DOI: 10.1002/chin.201608055 |
0.791 |
|
| 2015 |
Walton MC, Yang YF, Hong X, Houk KN, Overman LE. Ligand-Controlled Diastereoselective 1,3-Dipolar Cycloadditions of Azomethine Ylides with Methacrylonitrile. Organic Letters. PMID 26605985 DOI: 10.1021/Acs.Orglett.5B03171 |
0.368 |
|
| 2015 |
Pratsch G, Overman LE. Synthesis of 2,5-Diaryl-1,5-dienes from Allylic Bromides Using Visible-Light Photoredox Catalysis. The Journal of Organic Chemistry. PMID 26514061 DOI: 10.1021/Acs.Joc.5B01962 |
0.805 |
|
| 2015 |
Nawrat CC, Jamison CR, Slutskyy Y, MacMillan DW, Overman LE. Oxalates as Activating Groups for Alcohols in Visible Light Photoredox Catalysis: Formation of Quaternary Centers by Redox-Neutral Fragment Coupling. Journal of the American Chemical Society. 137: 11270-3. PMID 26322524 DOI: 10.1021/Jacs.5B07678 |
0.787 |
|
| 2015 |
Baumann M, Dieskau AP, Loertscher BM, Walton MC, Nam S, Xie J, Horne D, Overman LE. Tricyclic Analogues of Epidithiodioxopiperazine Alkaloids with Promising In Vitro and In Vivo Antitumor Activity. Chemical Science (Royal Society of Chemistry : 2010). 6: 4451-4457. PMID 26301062 DOI: 10.1039/C5Sc01536G |
0.785 |
|
| 2015 |
Canham SM, Hafensteiner BD, Lebsack AD, May-Dracka TL, Nam S, Stearns BA, Overman LE. Stereocontrolled enantioselective total synthesis of the [2+2] quadrigemine alkaloids. Tetrahedron. 71: 6424-6436. PMID 26257440 DOI: 10.1016/J.Tet.2015.02.080 |
0.847 |
|
| 2015 |
Pratsch G, Lackner GL, Overman LE. Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis. The Journal of Organic Chemistry. 80: 6025-36. PMID 26030520 DOI: 10.1021/Acs.Joc.5B00795 |
0.809 |
|
| 2015 |
Lackner GL, Quasdorf KW, Pratsch G, Overman LE. Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates By Visible-Light Photocatalysis. The Journal of Organic Chemistry. 80: 6012-24. PMID 26030387 DOI: 10.1021/Acs.Joc.5B00794 |
0.818 |
|
| 2015 |
Müller DS, Untiedt NL, Dieskau AP, Lackner GL, Overman LE. Correction to "constructing quaternary stereogenic centers using tertiary organocuprates and tertiary radicals. total synthesis of trans-clerodane natural products". Journal of the American Chemical Society. 137: 4874. PMID 25837968 DOI: 10.1021/jacs.5b01078 |
0.82 |
|
| 2015 |
Müller DS, Untiedt NL, Dieskau AP, Lackner GL, Overman LE. Constructing quaternary stereogenic centers using tertiary organocuprates and tertiary radicals. Total synthesis of trans-clerodane natural products. Journal of the American Chemical Society. 137: 660-3. PMID 25563555 DOI: 10.1021/Ja512527S |
0.828 |
|
| 2015 |
Baumann M, Dieskau AP, Loertscher BM, Walton MC, Nam S, Xie J, Horne D, Overman LE. Tricyclic analogues of epidithiodioxopiperazine alkaloids with promising in vitro and in vivo antitumor activity Chemical Science. 6: 4451-4457. DOI: 10.1039/c5sc01536g |
0.776 |
|
| 2015 |
Canham SM, Hafensteiner BD, Lebsack AD, May-Dracka TL, Nam S, Stearns BA, Overman LE. Stereocontrolled enantioselective total synthesis of the [2+2] quadrigemine alkaloids Tetrahedron. DOI: 10.1016/j.tet.2015.02.080 |
0.846 |
|
| 2015 |
Pratsch G, Lackner GL, Overman LE. ChemInform Abstract: Constructing Quaternary Carbons from N-(Acyloxy)phthalimide Precursors of Tertiary Radicals Using Visible-Light Photocatalysis. Cheminform. 46: no-no. DOI: 10.1002/chin.201544051 |
0.767 |
|
| 2015 |
Lackner GL, Quasdorf KW, Pratsch G, Overman LE. ChemInform Abstract: Fragment Coupling and the Construction of Quaternary Carbons Using Tertiary Radicals Generated From tert-Alkyl N-Phthalimidoyl Oxalates by Visible-Light Photocatalysis. Cheminform. 46: no-no. DOI: 10.1002/chin.201544040 |
0.798 |
|
| 2015 |
Quasdorf KW, Overman LE. ChemInform Abstract: Catalytic Enantioselective Synthesis of Quaternary Carbon Stereocentres Cheminform. 46: no-no. DOI: 10.1002/chin.201510326 |
0.835 |
|
| 2014 |
Quasdorf KW, Overman LE. Catalytic enantioselective synthesis of quaternary carbon stereocentres. Nature. 516: 181-91. PMID 25503231 DOI: 10.1038/Nature14007 |
0.812 |
|
| 2014 |
Shaghafi MB, Barrett DG, Willard FS, Overman LE. The insulin secretory action of novel polycyclic guanidines: discovery through open innovation phenotypic screening, and exploration of structure-activity relationships. Bioorganic & Medicinal Chemistry Letters. 24: 1031-6. PMID 24484900 DOI: 10.1016/J.Bmcl.2014.01.021 |
0.761 |
|
| 2014 |
Aron ZD, Ito T, May TL, Overman LE, Wang J. ChemInform Abstract: Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Rings: Coupled Dynamic Kinetic Epimerization and Chirality Transfer. Cheminform. 45: no-no. DOI: 10.1002/chin.201410134 |
0.833 |
|
| 2014 |
Lackner GL, Quasdorf KW, Overman LE. ChemInform Abstract: Direct Construction of Quaternary Carbons from Tertiary Alcohols via Photoredox-Catalyzed Fragmentation of tert-Alkyl N-Phthalimidoyl Oxalates. Cheminform. 45: no-no. DOI: 10.1002/chin.201410051 |
0.807 |
|
| 2014 |
Jabri SY, Overman LE. ChemInform Abstract: Enantioselective Total Syntheses of Plectosphaeroic Acids B (Ia) and C (Ib). Cheminform. 45: no-no. DOI: 10.1002/chin.201406223 |
0.79 |
|
| 2014 |
Schnermann MJ, Overman LE. Corrigendum: A Concise Synthesis of (−)-Aplyviolene Facilitated by a Strategic Tertiary Radical Conjugate Addition Angewandte Chemie International Edition. 53: 2527-2527. DOI: 10.1002/Anie.201308558 |
0.691 |
|
| 2013 |
Aron ZD, Ito T, May TL, Overman LE, Wang J. Enantioselective synthesis of angularly substituted 1-azabicylic rings: coupled dynamic kinetic epimerization and chirality transfer. The Journal of Organic Chemistry. 78: 9929-48. PMID 24090405 DOI: 10.1021/Jo4018099 |
0.847 |
|
| 2013 |
Lackner GL, Quasdorf KW, Overman LE. Direct construction of quaternary carbons from tertiary alcohols via photoredox-catalyzed fragmentation of tert-alkyl N-phthalimidoyl oxalates. Journal of the American Chemical Society. 135: 15342-5. PMID 24074152 DOI: 10.1021/Ja408971T |
0.808 |
|
| 2013 |
Jabri SY, Overman LE. Enantioselective total syntheses of plectosphaeroic acids B and C. The Journal of Organic Chemistry. 78: 8766-88. PMID 24007470 DOI: 10.1021/Jo4015479 |
0.824 |
|
| 2013 |
DeLorbe JE, Horne D, Jove R, Mennen SM, Nam S, Zhang FL, Overman LE. General approach for preparing epidithiodioxopiperazines from trioxopiperazine precursors: enantioselective total syntheses of (+)- and (-)-gliocladine C, (+)-leptosin D, (+)-T988C, (+)-bionectin A, and (+)-gliocladin A. Journal of the American Chemical Society. 135: 4117-28. PMID 23452236 DOI: 10.1021/Ja400315Y |
0.437 |
|
| 2013 |
Jabri SY, Overman LE. Enantioselective total synthesis of plectosphaeroic acid B. Journal of the American Chemical Society. 135: 4231-4. PMID 23452064 DOI: 10.1021/Ja401423J |
0.827 |
|
| 2013 |
Canham SM, France DJ, Overman LE. Total synthesis of (+)-sieboldine a: evolution of a pinacol-terminated cyclization strategy. The Journal of Organic Chemistry. 78: 9-34. PMID 22734821 DOI: 10.1021/Jo300872Y |
0.847 |
|
| 2013 |
Schnermann MJ, Untiedt NL, Jimenez-Oses G, Houk KN, Overman LE. ChemInform Abstract: Forming Tertiary Organolithiums and Organocuprates from Nitrile Precursors and Their Bimolecular Reactions with Carbon Electrophiles to Form Quaternary Carbon Stereocenters. Cheminform. 44: no-no. DOI: 10.1002/chin.201308040 |
0.803 |
|
| 2012 |
Wang H, Kohler P, Overman LE, Houk KN. Origins of stereoselectivities of dihydroxylations of cis-bicyclo[3.3.0]octenes. Journal of the American Chemical Society. 134: 16054-8. PMID 22954350 DOI: 10.1021/Ja3075538 |
0.402 |
|
| 2012 |
Schnermann MJ, Untiedt NL, Jiménez-Osés G, Houk KN, Overman LE. Forming tertiary organolithiums and organocuprates from nitrile precursors and their bimolecular reactions with carbon electrophiles to form quaternary carbon stereocenters. Angewandte Chemie (International Ed. in English). 51: 9581-6. PMID 22927041 DOI: 10.1002/Anie.201205001 |
0.828 |
|
| 2012 |
Schnermann MJ, Overman LE. A concise synthesis of (-)-aplyviolene facilitated by a strategic tertiary radical conjugate addition. Angewandte Chemie (International Ed. in English). 51: 9576-80. PMID 22926995 DOI: 10.1002/Anie.201204977 |
0.735 |
|
| 2012 |
Cannon JS, Overman LE. Is there no end to the total syntheses of strychnine? Lessons learned in strategy and tactics in total synthesis. Angewandte Chemie (International Ed. in English). 51: 4288-311. PMID 22431197 DOI: 10.1002/Anie.201107385 |
0.69 |
|
| 2012 |
Cannon JS, Olson AC, Overman LE, Solomon NS. Palladium(II)-catalyzed enantioselective synthesis of 2-vinyl oxygen heterocycles. The Journal of Organic Chemistry. 77: 1961-73. PMID 22316285 DOI: 10.1021/Jo202553A |
0.82 |
|
| 2012 |
Cannon JS, Frederich JH, Overman LE. Palladacyclic imidazoline-naphthalene complexes: synthesis and catalytic performance in Pd(II)-catalyzed enantioselective reactions of allylic trichloroacetimidates. The Journal of Organic Chemistry. 77: 1939-51. PMID 22288535 DOI: 10.1021/Jo2025724 |
0.83 |
|
| 2012 |
Cannon JS, Overman LE. ChemInform Abstract: Is There No End to the Total Syntheses of Strychnine? Lessons Learned in Strategy and Tactics in Total Synthesis Cheminform. 43: no-no. DOI: 10.1002/chin.201234207 |
0.642 |
|
| 2012 |
Cannon JS, Olson AC, Overman LE, Solomon NS. ChemInform Abstract: Palladium(II)-Catalyzed Enantioselective Synthesis of 2-Vinyl Oxygen Heterocycles. Cheminform. 43: no-no. DOI: 10.1002/chin.201225148 |
0.783 |
|
| 2012 |
Cannon JS, Overman LE. Kein Ende für Totalsynthesen von Strychnin in Sicht? Lektionen für Strategien und Methoden in der Totalsynthese Angewandte Chemie. 124: 4362-4386. DOI: 10.1002/Ange.201107385 |
0.641 |
|
| 2011 |
Canham SM, Overman LE, Tanis PS. Identification of an Unexpected 2-Oxonia[3,3]sigmatropic Rearrangement/Aldol Pathway in the Formation of Oxacyclic Rings. Total Synthesis of (+)-Aspergillin PZ. Tetrahedron. 67: 9837-9843. PMID 22518066 DOI: 10.1016/J.Tet.2011.09.079 |
0.833 |
|
| 2011 |
Schnermann MJ, Beaudry CM, Genung NE, Canham SM, Untiedt NL, Karanikolas BD, Sütterlin C, Overman LE. Divergent synthesis and chemical reactivity of bicyclic lactone fragments of complex rearranged spongian diterpenes. Journal of the American Chemical Society. 133: 17494-503. PMID 21988207 DOI: 10.1021/Ja207727H |
0.841 |
|
| 2011 |
Schnermann MJ, Overman LE. Enantioselective total synthesis of aplyviolene. Journal of the American Chemical Society. 133: 16425-7. PMID 21936525 DOI: 10.1021/Ja208018S |
0.742 |
|
| 2011 |
DeLorbe JE, Jabri SY, Mennen SM, Overman LE, Zhang FL. Enantioselective total synthesis of (+)-gliocladine C: convergent construction of cyclotryptamine-fused polyoxopiperazines and a general approach for preparing epidithiodioxopiperazines from trioxopiperazine precursors. Journal of the American Chemical Society. 133: 6549-52. PMID 21473649 DOI: 10.1021/Ja201789V |
0.853 |
|
| 2011 |
Martin CL, Nakamura S, Otte R, Overman LE. Total synthesis of (+)-condylocarpine, (+)-isocondylocarpine, and (+)-tubotaiwine. Organic Letters. 13: 138-41. PMID 21133399 DOI: 10.1021/Ol102709S |
0.608 |
|
| 2011 |
Cannon JS, Kirsch SF, Overman LE. ChemInform Abstract: Catalytic Asymmetric Synthesis of Chiral Allylic Esters. Cheminform. 42: no-no. DOI: 10.1002/chin.201112045 |
0.797 |
|
| 2011 |
Overman LE, Humphreys PG, Welmaker GS. The aza-cope/mannich reaction Organic Reactions. 75: 747-820. DOI: 10.1002/0471264180.Or075.04 |
0.786 |
|
| 2010 |
Altman RA, Nilsson BL, Overman LE, Read de Alaniz J, Rohde JM, Taupin V. Total synthesis of (+)-nankakurines A and B and (±)-5-epi-nankakurine A. The Journal of Organic Chemistry. 75: 7519-34. PMID 20958075 DOI: 10.1021/Jo101619D |
0.815 |
|
| 2010 |
Cannon JS, Kirsch SF, Overman LE, Sneddon HF. Mechanism of the cobalt oxazoline palladacycle (COP)-catalyzed asymmetric synthesis of allylic esters. Journal of the American Chemical Society. 132: 15192-203. PMID 20942424 DOI: 10.1021/Ja106688J |
0.79 |
|
| 2010 |
Cannon JS, Kirsch SF, Overman LE. Catalytic asymmetric synthesis of chiral allylic esters. Journal of the American Chemical Society. 132: 15185-91. PMID 20942420 DOI: 10.1055/S-2005-869916 |
0.799 |
|
| 2010 |
Overman LE, Rosen MD. Terminating Catalytic Asymmetric Heck Cyclizations by Stereoselective Intramolecular Capture of η-Allylpalladium Intermediates: Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers. Tetrahedron. 66: 6514-6525. PMID 20725641 DOI: 10.1016/J.Tet.2010.05.048 |
0.7 |
|
| 2010 |
Canham SM, France DJ, Overman LE. Total synthesis of (+)-sieboldine A. Journal of the American Chemical Society. 132: 7876-7. PMID 20527933 DOI: 10.1021/Ja103666N |
0.827 |
|
| 2010 |
Schnermann MJ, Beaudry CM, Egorova AV, Polishchuk RS, Sütterlin C, Overman LE. Golgi-modifying properties of macfarlandin E and the synthesis and evaluation of its 2,7-dioxabicyclo[3.2.1]octan-3-one core. Proceedings of the National Academy of Sciences of the United States of America. 107: 6158-63. PMID 20332207 DOI: 10.1073/Pnas.1001421107 |
0.652 |
|
| 2010 |
Martin CL, Overman LE, Rohde JM. Total synthesis of (+/-)- and (-)-actinophyllic acid. Journal of the American Chemical Society. 132: 4894-906. PMID 20218696 DOI: 10.1021/Ja100178U |
0.658 |
|
| 2010 |
Ito T, Overman LE, Wang J. Enantioselective synthesis of angularly substituted 1-azabicyclic ring systems: dynamic kinetic resolution using aza-Cope rearrangements. Journal of the American Chemical Society. 132: 3272-3. PMID 20175519 DOI: 10.1021/Ja100607Z |
0.766 |
|
| 2010 |
Overman LE, Tanis PS. Origin of stereocontrol in the construction of the 12-oxatricyclo[6.3.1.0(2,7)]dodecane ring system by Prins-pinacol reactions. The Journal of Organic Chemistry. 75: 455-63. PMID 20000652 DOI: 10.1021/Jo9024144 |
0.79 |
|
| 2010 |
Overman LE. Cluster preface: Stereoselective synthesis of stereogenic quaternary carbons: A formidable challenge and remarkable recent progress Synlett. 1692-1693. DOI: 10.1055/S-0030-1258097 |
0.346 |
|
| 2010 |
Overman L, Canham S, France D. Synthesis of (+)-Sieboldine A Synfacts. 2010: 0983-0983. DOI: 10.1055/S-0030-1257929 |
0.799 |
|
| 2010 |
Olson AC, Overman LE, Sneddon HF, Ziller JW. Enantioselective Allylic Etherification Using a Novel COPCatalyst Synfacts. 2010: 442-442. DOI: 10.1055/S-0029-1219483 |
0.471 |
|
| 2010 |
Corminboeuf O, Overman LE, Pennington LD. Synthesis of Briarellins E and F Synfacts. 2010: 135-135. DOI: 10.1055/S-0029-1219024 |
0.703 |
|
| 2010 |
Canham SM, France DJ, Overman LE. ChemInform Abstract: Total Synthesis of (+)-Sieboldine A. Cheminform. 41. DOI: 10.1002/chin.201042201 |
0.389 |
|
| 2010 |
Martin CL, Overman LE, Rohde JM. ChemInform Abstract: Total Synthesis of (.+-.)- and (-)-Actinophyllic Acid. Cheminform. 41: no-no. DOI: 10.1002/chin.201031204 |
0.578 |
|
| 2010 |
Ito T, Overman LE, Wang J. ChemInform Abstract: Enantioselective Synthesis of Angularly Substituted 1-Azabicyclic Ring Systems: Dynamic Kinetic Resolution Using Aza-Cope Rearrangements. Cheminform. 41: no-no. DOI: 10.1002/chin.201031125 |
0.749 |
|
| 2010 |
Olson AC, Overman LE, Sneddon HF, Ziller JW. ChemInform Abstract: Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols. Cheminform. 41. DOI: 10.1002/chin.201018073 |
0.662 |
|
| 2010 |
Gahman TC, Overman LE. ChemInform Abstract: Stereoselective Synthesis of Carbocyclic Ring Systems by Pinacol-Terminated Prins Cyclizations. Cheminform. 33: no-no. DOI: 10.1002/chin.200250061 |
0.344 |
|
| 2010 |
Overman LE, Remarchuk TP. ChemInform Abstract: Catalytic Asymmetric Intramolecular Aminopalladation: Enantioselective Synthesis of Vinyl-Substituted 2-Oxazolidinones, 2-Imidazolidinones, and 2-Pyrrolidinones. Cheminform. 33: no-no. DOI: 10.1002/chin.200224035 |
0.859 |
|
| 2010 |
Kamenecka TM, Overman LE, Ly Sakata SK. ChemInform Abstract: Construction of Substituted Cyclohexanones by Reductive Cyclization of 7-Oxo-2,8-alkadienyl Esters. Cheminform. 33: no-no. DOI: 10.1002/chin.200222082 |
0.356 |
|
| 2010 |
Govek SP, Overman LE. ChemInform Abstract: Total Synthesis of Asperazine. Cheminform. 33: no-no. DOI: 10.1002/chin.200204218 |
0.814 |
|
| 2010 |
Overman LE, Paone DV. ChemInform Abstract: Enantioselective Total Syntheses of Ditryptophenaline and ent-WIN 64821. Cheminform. 33: no-no. DOI: 10.1002/chin.200204217 |
0.359 |
|
| 2010 |
MacMillan DWC, Overman LE, Pennington LD. ChemInform Abstract: A General Strategy for the Synthesis of Cladiellin Diterpenes: Enantioselective Total Syntheses of 6-Acetoxycladiell-7(16),11-dien-3-ol (Deacetoxyalcyonin Acetate) (I), Cladiell-11-ene-3,6,7-triol (II), Sclerophytin A (III), and the I Cheminform. 33: no-no. DOI: 10.1002/chin.200204186 |
0.74 |
|
| 2010 |
O'Connor SJ, Overman LE, Rucker PV. ChemInform Abstract: Use of Sequential Intramolecular Heck Cyclizations for Preparing Bicyclo[3.2.1]octane Fragments of Tetracyclic Stemodane and Stemarane Diterpenes. Cheminform. 32: no-no. DOI: 10.1002/chin.200142213 |
0.328 |
|
| 2010 |
Overman LE, Wolfe JP. ChemInform Abstract: Synthesis of Polycyclic Guanidines by Cyclocondensation Reactions of N-Amidinyliminium Ions. Cheminform. 32: no-no. DOI: 10.1002/chin.200137152 |
0.563 |
|
| 2010 |
Cohen F, MacMillan DWC, Overman LE, Romero A. ChemInform Abstract: Stereoselection in the Prins-Pinacol Synthesis of Acyltetrahydrofurans. Cheminform. 32: no-no. DOI: 10.1002/chin.200133121 |
0.428 |
|
| 2010 |
Kamatani A, Overman LE. ChemInform Abstract: A New Asymmetric Synthesis of trans-Hydroisoquinolones. Cheminform. 32: no-no. DOI: 10.1002/chin.200131146 |
0.373 |
|
| 2010 |
Donde Y, Overman LE. ChemInform Abstract: Asymmetric Intramolecular Heck Reactions Cheminform. 32: no-no. DOI: 10.1002/chin.200129263 |
0.309 |
|
| 2010 |
Hanaki N, Link JT, MacMillian DWC, Overman LE, Trankle WG, Wurster JA. ChemInform Abstract: Stereoselection in the Prins-Pinacol Synthesis of 2,2-Disubstituted 4-Acyltetrahydrofurans. Enantioselective Synthesis of (-)-Citreoviral (XII). Cheminform. 31: no-no. DOI: 10.1002/chin.200016259 |
0.446 |
|
| 2010 |
Bogenstaetter M, Limberg A, Overman LE, Tomasi AL. ChemInform Abstract: Enantioselective Total Synthesis of the Kinesin Motor Protein Inhibitor Adociasulfate 1. Cheminform. 31: no-no. DOI: 10.1002/chin.200013150 |
0.794 |
|
| 2010 |
Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. ChemInform Abstract: Total Synthesis of (.+-.)-Gelsemine. Cheminform. 31: no-no. DOI: 10.1002/chin.200003222 |
0.389 |
|
| 2010 |
Overman LE, Paone DV, Stearns BA. ChemInform Abstract: Direct Stereo- and Enantiocontrolled Synthesis of Vicinal Stereogenic Quaternary Carbon Centers. Total Syntheses of meso- and (-)-Chimonanthine and (+)-Calycanthine. Cheminform. 30: no-no. DOI: 10.1002/chin.199952217 |
0.792 |
|
| 2010 |
Coffey DS, McDonald AI, Overman LE, Stappenbeck F. ChemInform Abstract: Enantioselective Total Synthesis of 13,14,15-Isocrambescidin 800 (I). Cheminform. 30: no-no. DOI: 10.1002/chin.199950216 |
0.426 |
|
| 2010 |
McDonald AI, Overman LE. ChemInform Abstract: Tuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis- or trans-1-Oxo- and 1-Iminohexahydropyrrolo[1,2-c]pyrimidines. Cheminform. 30: no-no. DOI: 10.1002/chin.199933173 |
0.304 |
|
| 2010 |
Hollis TK, Overman LE. ChemInform Abstract: Palladium Catalyzed Enantioselective Rearrangement of Allylic Imidates to Allylic Amides Cheminform. 30: no-no. DOI: 10.1002/chin.199932290 |
0.688 |
|
| 2010 |
Franklin AS, Ly SK, Mackin GH, Overman LE, Shaka AJ. ChemInform Abstract: Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B. Cheminform. 30: no-no. DOI: 10.1002/chin.199929206 |
0.374 |
|
| 2010 |
Cloninger MJ, Overman LE. ChemInform Abstract: Stereocontrolled Synthesis of Trisubstituted Tetrahydropyrans. Cheminform. 30: no-no. DOI: 10.1002/chin.199928167 |
0.41 |
|
| 2010 |
Brosius AD, Overman LE, Schwink L. ChemInform Abstract: Total Synthesis of (+)-Aloperine. Use of a Nitrogen-Bound Silicon Tether in an Intramolecular Diels-Alder Reaction. Cheminform. 30: no-no. DOI: 10.1002/chin.199926233 |
0.359 |
|
| 2010 |
ASHIMORI A, BACHAND B, OVERMAN LE, POON DJ. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Investigations of Intramolecular Heck Reactions of (E)-α,β-Unsaturated 2-Haloanilides and Analogues to Form Enantioenriched Spirocyclic Products. Cheminform. 29: no-no. DOI: 10.1002/chin.199846130 |
0.337 |
|
| 2010 |
ASHIMORI A, BACHAND B, CALTER MA, GOVEK SP, OVERMAN LE, POON DJ. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers. Exploratory Studies of Intramolecular Heck Reactions of (Z)-α,β-Unsaturated Anilides and Mechanistic Investigations of Asymmetric Heck Reactions Proceeding via Neutral Inter Cheminform. 29: no-no. DOI: 10.1002/chin.199845139 |
0.829 |
|
| 2010 |
HYNES JJ, OVERMAN LE, NASSER T, RUCKER PV. ChemInform Abstract: Intramolecular Heck Cyclization of α-Sulfenyl Enol Triflates. Asymmetric Synthesis of a Pentacyclic Cardenolide Precursor Having Functionality at C-11. Cheminform. 29: no-no. DOI: 10.1002/chin.199838229 |
0.347 |
|
| 2010 |
OVERMAN LE, RUCKER PV. ChemInform Abstract: Enantioselective Synthesis of Cardenolide Precursors Using an Intramolecular Heck Reaction. Cheminform. 29: no-no. DOI: 10.1002/chin.199838228 |
0.43 |
|
| 2010 |
OVERMAN LE, TOMASI AL. ChemInform Abstract: Enantioselective Total Synthesis of Hispidospermidin. Cheminform. 29: no-no. DOI: 10.1002/chin.199833260 |
0.849 |
|
| 2010 |
ABELMAN MM, KADO N, OVERMAN LE, SARKAR AK. ChemInform Abstract: Synthesis of a Phenolic Analogue of Aphidicolin. Diminished Stereoselection in Intramolecular 6-Exo Heck Reactions of Substrates Having a Hydrocarbon Tether. Cheminform. 29: no-no. DOI: 10.1002/chin.199814094 |
0.422 |
|
| 2010 |
HOLLIS TK, OVERMAN LE. ChemInform Abstract: Cyclopalladated Ferrocenyl Amines as Enantioselective Catalysts for the Rearrangement of Allylic Imidates to Allylic Amides. Cheminform. 29: no-no. DOI: 10.1002/chin.199811042 |
0.628 |
|
| 2010 |
OVERMAN LE, ROGERS BN, TELLEW JE, TRENKLE WC. ChemInform Abstract: Stereocontrolled Synthesis of the Tetracyclic Core of the Bisguanidine Alkaloids Palau′amine and Styloguanidine. Cheminform. 28: no-no. DOI: 10.1002/chin.199748259 |
0.8 |
|
| 2010 |
OVERMAN LE, ZIPP GG. ChemInform Abstract: Allylic Transposition of Alcohol and Amine Functionality by Thermal or Palladium(II)-Catalyzed Rearrangements of Allylic N- Benzoylbenzimidates. Cheminform. 28: no-no. DOI: 10.1002/chin.199735096 |
0.753 |
|
| 2010 |
CALTER M, HOLLIS TK, OVERMAN LE, ZILLER J, ZIPP GG. ChemInform Abstract: First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides. Cheminform. 28: no-no. DOI: 10.1002/chin.199728055 |
0.813 |
|
| 2010 |
BERGER D, OVERMAN LE, RENHOWE PA. ChemInform Abstract: Total Synthesis of (+)-Isolaurepinnacin. Use of Acetal-Alkene Cyclizations to Prepare Highly Functionalized Seven-Membered Cyclic Ethers. Cheminform. 28: no-no. DOI: 10.1002/chin.199725184 |
0.409 |
|
| 2010 |
BROSIUS AD, OVERMAN LE. ChemInform Abstract: Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration. Cheminform. 28: no-no. DOI: 10.1002/chin.199723249 |
0.371 |
|
| 2010 |
OVERMAN LE, POON DJ. ChemInform Abstract: Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights. Cheminform. 28: no-no. DOI: 10.1002/chin.199723143 |
0.34 |
|
| 2010 |
OVERMAN LE, TELLEW JE. ChemInform Abstract: Synthesis of 2-Azatricyclo(5.2.1.04,10)decanes and 2,5-Diazatricyclo(5. 2.1.04,10)decanes by Intramolecular Azomethine Ylide Cycloadditions. Cheminform. 28: no-no. DOI: 10.1002/chin.199716153 |
0.438 |
|
| 2010 |
MACMILLAN DWC, OVERMAN LE. ChemInform Abstract: Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene. Cheminform. 27: no-no. DOI: 10.1002/chin.199608204 |
0.436 |
|
| 2010 |
BRATZ M, BULLOCK WH, OVERMAN LE, TAKEMOTO T. ChemInform Abstract: Total Synthesis of (+)-Laurencin. Use of Acetal-Vinyl Sulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers. Cheminform. 26: no-no. DOI: 10.1002/chin.199539259 |
0.394 |
|
| 2010 |
KNIGHT SD, OVERMAN LE, PAIRAUDEAU G. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 28. Asymmetric Total Syntheses of (-)- and (+)-Strychnine (IX) and the Wieland-Gumlich Aldehyde (VII). Cheminform. 26: no-no. DOI: 10.1002/chin.199538266 |
0.417 |
|
| 2010 |
OVERMAN LE, RABINOWITZ MH, RENHOWE PA. ChemInform Abstract: Enantioselective Total Synthesis of (-)-Ptilomycalin A. Cheminform. 26: no-no. DOI: 10.1002/chin.199531218 |
0.426 |
|
| 2010 |
KNIGHT SD, OVERMAN LE. ChemInform Abstract: Preparation of Spirocyclic Polyethers by Intramolecular Heck Reactions. Cheminform. 26: no-no. DOI: 10.1002/chin.199526146 |
0.323 |
|
| 2010 |
OVERMAN LE, RENHOWE PA. ChemInform Abstract: Regioselective Opening of Terminal Epoxides with 2-(Trialkylsilyl) allyl Organometallic Reagents. Cheminform. 26: no-no. DOI: 10.1002/chin.199504070 |
0.346 |
|
| 2010 |
KAMENECKA TM, OVERMAN LE. ChemInform Abstract: An Enantioselective Approach to the Synthesis of Manzamine A. Cheminform. 25: no-no. DOI: 10.1002/chin.199445217 |
0.342 |
|
| 2010 |
HONG CY, OVERMAN LE. ChemInform Abstract: Preparation of Opium Alkaloids by Palladium-Catalyzed Bis-Cyclizations. Formal Total Synthesis of Morphine. Cheminform. 25: no-no. DOI: 10.1002/chin.199442242 |
0.388 |
|
| 2010 |
OVERMAN LE. ChemInform Abstract: Application of Intramolecular Heck Reactions for Forming Congested Quaternary Carbon Centers in Complex Molecule Total Synthesis Cheminform. 25: no-no. DOI: 10.1002/chin.199441287 |
0.348 |
|
| 2010 |
LASCHAT S, NARJES F, OVERMAN LE. ChemInform Abstract: Application of Intramolecular Heck Reactions to the Preparation of Steroid and Terpene Intermediates Having cis A-B Ring Fusions. Model Studies for the Total Synthesis of Complex Cardenolides. Cheminform. 25: no-no. DOI: 10.1002/chin.199419059 |
0.366 |
|
| 2010 |
ASHIMORI A, MATSUURA T, OVERMAN LE, POON DJ. ChemInform Abstract: Catalytic Asymmetric Synthesis of Either Enantiomer of Physostigmine. Formation of Quaternary Carbon Centers with High Enantioselection by Intramolecular Heck Reactions of (Z)-2-Butenanilides. Cheminform. 25: no-no. DOI: 10.1002/chin.199416046 |
0.431 |
|
| 2010 |
HONG CY, KADO N, OVERMAN LE. ChemInform Abstract: Asymmetric Synthesis of Either Enantiomer of Opium Alkaloids and Morphinans. Total Synthesis of (-)- and (+)-Dihydrocodeinone and (-)- and (+)-Morphine. Cheminform. 25: no-no. DOI: 10.1002/chin.199409257 |
0.361 |
|
| 2010 |
MONTGOMERY J, OVERMAN LE. ChemInform Abstract: Introduction of the 2-(Phenylthio)ethyl, 2-(Phenylsulfinyl)ethyl, and 2,2-Bis(phenylthio)ethyl Substituents into Cyclic Ketones. Cheminform. 25: no-no. DOI: 10.1002/chin.199409098 |
0.37 |
|
| 2010 |
KUCERA DJ, O'CONNOR SJ, OVERMAN LE. ChemInform Abstract: Total Synthesis of (.+-.)-Scopadulcic Acid A. An Illustration of the Utility of Palladium-Catalyzed Polyene Cyclizations. Cheminform. 25: no-no. DOI: 10.1002/chin.199406209 |
0.39 |
|
| 2010 |
KNIGHT SD, OVERMAN LE, PAIRAUDEAU G. ChemInform Abstract: Applications of Cationic Aza-Cope Rearrangements. Part 26. Enantioselective Total Synthesis of (-)-Strychnine. Cheminform. 25: no-no. DOI: 10.1002/chin.199404253 |
0.392 |
|
| 2010 |
BERGER D, OVERMAN LE, RENHOWE PA. ChemInform Abstract: Enantioselective Total Synthesis of (+)-Isolaurepinnacin. Cheminform. 25: no-no. DOI: 10.1002/chin.199403229 |
0.426 |
|
| 2010 |
OVERMAN LE, SHIM J. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Part 25. Total Synthesis of Amaryllidaceae Alkaloids of the 5,11- Methanomorphanthridine Type. Efficient Total Synthesis of (-)- Pancracine (-)-(I) and (.+-.)-Pancracine. Cheminform. 24: no-no. DOI: 10.1002/chin.199351268 |
0.386 |
|
| 2010 |
OVERMAN LE, RABINOWITZ MH. ChemInform Abstract: Studies Toward the Total Synthesis of (+)-Ptilomycalin A. Use of a Tethered Biginelli Condensation for the Preparation of an Advanced Tricyclic Intermediate. Cheminform. 24: no-no. DOI: 10.1002/chin.199339285 |
0.397 |
|
| 2010 |
HIRST GC, JOHNSON TOJ, OVERMAN LE. ChemInform Abstract: First Total Synthesis of Lycopodium Alkaloids of the Magellanane Group. Enantioselective Total Syntheses of (-)-Magellanine and (+)- Magellaninone. Cheminform. 24: no-no. DOI: 10.1002/chin.199335295 |
0.366 |
|
| 2010 |
BERGER D, OVERMAN LE. ChemInform Abstract: Preparation of Seven-Membered Cyclic Ethers Containing Halogenated Side Chains by Acetal - Alkene Cyclizations. Cheminform. 24: no-no. DOI: 10.1002/chin.199322213 |
0.32 |
|
| 2010 |
OVERMAN LE, ABELMAN MM, KUCERA DJ, TRAN VD, RICCA DJ. ChemInform Abstract: Palladium-Catalyzed Polyene Cyclizations Cheminform. 24: no-no. DOI: 10.1002/chin.199311323 |
0.401 |
|
| 2010 |
OVERMAN LE, SARKAR AK. ChemInform Abstract: Iodide-Promoted Aldiminium Ion-Alkyne Cyclizations. A Convenient Synthesis of Substituted Tetrahydropyridines and 3- Alkylidenepiperidines. Cheminform. 24: no-no. DOI: 10.1002/chin.199302196 |
0.328 |
|
| 2010 |
ASHIMORI A, OVERMAN LE. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quarternary Carbon Centers. Palladium-Catalyzed Formation of Either Enantiomer of Spirooxindoles and Related Spirocyclics Using a Single Enantiomer of a Chiral Diphosphine Ligand. Cheminform. 24: no-no. DOI: 10.1002/chin.199302176 |
0.379 |
|
| 2010 |
FLANN CJ, OVERMAN LE, SARKAR AK. ChemInform Abstract: Synthesis of 3-Acyl-3-alkyloxindoles. Cheminform. 23: no-no. DOI: 10.1002/chin.199230144 |
0.41 |
|
| 2010 |
OVERMAN LE, SHIM J. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangement. Part 24. First Total Synthesis of Amaryllidaceae Alkaloids of the 5,11- Methanomorphanthridine Type. An Efficient Total Synthesis of (.+-.)- Pancracine (I). Cheminform. 23: no-no. DOI: 10.1002/chin.199203253 |
0.386 |
|
| 2010 |
BROWN MJ, HARRISON T, OVERMAN LE. ChemInform Abstract: General Approach to Halogenated Tetrahydrofuran Natural Products from Red Algae of the Genus Laurencia. Total Synthesis of (.+-.)-trans- Kumausyne and Demonstration of an Asymmetric Synthesis Strategy. Cheminform. 22: no-no. DOI: 10.1002/chin.199142159 |
0.363 |
|
| 2010 |
BROWN MJ, HARRISON T, HERRINTON PM, HOPKINS MH, HUTCHINSON KD, MISHRA P, OVERMAN LE. ChemInform Abstract: Acid-Promoted Reaction of Cyclic Allylic Diols with Carbonyl Compounds. Stereoselective Ring-Enlarging Tetrahydrofuran Annulations. Cheminform. 22: no-no. DOI: 10.1002/chin.199142158 |
0.335 |
|
| 2010 |
BROWN MJ, OVERMAN LE. ChemInform Abstract: Preparation of 3-Amino-4-(hydroxymethyl)azetidin-2-ones from the Reaction of Glycine Enolates with Imines of a Glycoaldehyde. Cheminform. 22: no-no. DOI: 10.1002/chin.199130155 |
0.315 |
|
| 2009 |
Olson AC, Overman LE, Sneddon HF, Ziller JW. Catalytic Asymmetric Synthesis of Branched Chiral Allylic Phenyl Ethers from (E)-Allylic Alcohols. Advanced Synthesis & Catalysis. 351: 3186-3192. PMID 23795152 DOI: 10.1002/Adsc.200900678 |
0.706 |
|
| 2009 |
Dunn TB, Ellis JM, Kofink CC, Manning JR, Overman LE. Asymmetric construction of rings A-D of daphnicyclidin-type alkaloids. Organic Letters. 11: 5658-61. PMID 19904991 DOI: 10.1021/Ol902373M |
0.378 |
|
| 2009 |
Corminboeuf O, Overman LE, Pennington LD. A unified strategy for enantioselective total synthesis of cladiellin and briarellin diterpenes: total synthesis of briarellins E and F and the putative structure of alcyonin and revision of its structure assignment. The Journal of Organic Chemistry. 74: 5458-70. PMID 19534538 DOI: 10.1021/Jo9010156 |
0.752 |
|
| 2009 |
Taniguchi T, Martin CL, Monde K, Nakanishi K, Berova N, Overman LE. Absolute configuration of actinophyllic acid as determined through chiroptical data. Journal of Natural Products. 72: 430-2. PMID 19220031 DOI: 10.1021/Np800665S |
0.534 |
|
| 2009 |
Overman L, Nilsson B, de Alaniz J, Rohde J. Synthesis of Nankakurines A and B Synfacts. 2009: 0246-0246. DOI: 10.1055/S-0028-1087692 |
0.371 |
|
| 2009 |
Ellis JM, Overman LE, Tanner HR, Wang J. ChemInform Abstract: A Versatile Synthesis of Unsymmetrical 3,3′-Bioxindoles: Stereoselective Mukaiyama Aldol Reactions of 2-Siloxyindoles with Isatins. Cheminform. 40. DOI: 10.1002/chin.200915115 |
0.784 |
|
| 2009 |
Dounay AB, Overman LE. The Asymmetric Intramolecular Mizoroki-Heck Reaction in Natural Product Total Synthesis The Mizoroki-Heck Reaction. 533-568. DOI: 10.1002/9780470716076.ch16 |
0.373 |
|
| 2008 |
Ellis JM, Overman LE, Tanner HR, Wang J. A versatile synthesis of unsymmetrical 3,3'-bioxindoles: stereoselective Mukaiyama aldol reactions of 2-siloxyindoles with isatins. The Journal of Organic Chemistry. 73: 9151-4. PMID 18855482 DOI: 10.1021/Jo801867W |
0.801 |
|
| 2008 |
Nilsson BL, Overman LE, Read de Alaniz J, Rohde JM. Enantioselective total syntheses of nankakurines A and B: confirmation of structure and establishment of absolute configuration. Journal of the American Chemical Society. 130: 11297-9. PMID 18680252 DOI: 10.1021/Ja804624U |
0.702 |
|
| 2008 |
Martin CL, Overman LE, Rohde JM. Total synthesis of (+/-)-actinophyllic acid. Journal of the American Chemical Society. 130: 7568-9. PMID 18491907 DOI: 10.1021/Ja803158Y |
0.692 |
|
| 2008 |
Overman LE, Roberts SW, Sneddon HF. Catalytic asymmetric synthesis of allylic thiol derivatives. Organic Letters. 10: 1485-8. PMID 18336036 DOI: 10.1021/Ol8002942 |
0.448 |
|
| 2008 |
Dounay AB, Humphreys PG, Overman LE, Wrobleski AD. Total synthesis of the strychnos alkaloid (+)-minfiensine: tandem enantioselective intramolecular Heck-iminium ion cyclization. Journal of the American Chemical Society. 130: 5368-77. PMID 18303837 DOI: 10.1021/Ja800163V |
0.45 |
|
| 2008 |
Overman LE, Roberts SW, Sneddon HF. Palladium-Catalyzed Enantioselective Synthesis of Allylic Thiol Derivatives Synfacts. 2008: 612-612. DOI: 10.1055/S-2008-1072626 |
0.543 |
|
| 2008 |
Martin CL, Overman LE, Rohde JM. Synthesis of (±)-Actinophyllic Acid Synfacts. 2010: 862-862. DOI: 10.1055/S-0030-1257764 |
0.555 |
|
| 2008 |
Overman L, Dounay A, Humphreys P, Wrobleski A. Synthesis of (+)-Minfiensine Synfacts. 2008: 1128-1128. DOI: 10.1055/S-0028-1083414 |
0.491 |
|
| 2008 |
Martin CL, Overman LE, Rohde JM. ChemInform Abstract: Total Synthesis of (.+-.)-Actinophyllic Acid. Cheminform. 39. DOI: 10.1002/chin.200842198 |
0.578 |
|
| 2008 |
Dounay AB, Humphreys PG, Overman LE, Wrobleski AD. ChemInform Abstract: Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck-Iminium Ion Cyclization. Cheminform. 39. DOI: 10.1002/chin.200835188 |
0.342 |
|
| 2008 |
Overman LE, Roberts SW, Sneddon HF. ChemInform Abstract: Catalytic Asymmetric Synthesis of Allylic Thiol Derivatives. Cheminform. 39. DOI: 10.1002/chin.200832058 |
0.439 |
|
| 2008 |
Kodanko JJ, Hiebert S, Peterson EA, Sung L, Overman LE, de Moura Linck V, Goerck GC, Amador TA, Leal MB, Elisabetsky E. ChemInform Abstract: Synthesis of All Low-Energy Stereoisomers of the Tris(pyrrolidinoindoline) Alkaloid Hodgkinsine and Preliminary Assessment of Their Antinociceptive Activity. Cheminform. 39. DOI: 10.1002/chin.200807176 |
0.787 |
|
| 2008 |
Overman LE, et al. ea. ChemInform Abstract: Total Synthesis of (-)-Sarain A. Cheminform. 39. DOI: 10.1002/chin.200806191 |
0.389 |
|
| 2007 |
Overman LE, Sato T. Construction of epidithiodioxopiperazines by directed oxidation of hydroxyproline-derived dioxopiperazines. Organic Letters. 9: 5267-70. PMID 18001051 DOI: 10.1021/Ol702518T |
0.368 |
|
| 2007 |
Lanman BA, Overman LE, Paulini R, White NS. On the structure of palau'amine: evidence for the revised relative configuration from chemical synthesis. Journal of the American Chemical Society. 129: 12896-900. PMID 17902668 DOI: 10.1021/Ja074939X |
0.632 |
|
| 2007 |
Kodanko JJ, Hiebert S, Peterson EA, Sung L, Overman LE, de Moura Linck V, Goerck GC, Amador TA, Leal MB, Elisabetsky E. Synthesis of all low-energy stereoisomers of the tris(pyrrolidinoindoline) alkaloid hodgkinsine and preliminary assessment of their antinociceptive activity. The Journal of Organic Chemistry. 72: 7909-14. PMID 17887704 DOI: 10.1021/Jo7013643 |
0.84 |
|
| 2007 |
Becker MH, Chua P, Downham R, Douglas CJ, Garg NK, Hiebert S, Jaroch S, Matsuoka RT, Middleton JA, Ng FW, Overman LE. Total synthesis of (-)-sarain A. Journal of the American Chemical Society. 129: 11987-2002. PMID 17850086 DOI: 10.1021/Ja074300T |
0.786 |
|
| 2007 |
Steven A, Overman LE. Total synthesis of complex cyclotryptamine alkaloids: stereocontrolled construction of quaternary carbon stereocenters. Angewandte Chemie (International Ed. in English). 46: 5488-508. PMID 17591737 DOI: 10.1002/Anie.200700612 |
0.426 |
|
| 2007 |
Watson MP, Overman LE, Bergman RG. Kinetic and computational analysis of the palladium(II)-catalyzed asymmetric allylic trichloroacetimidate rearrangement: development of a model for enantioselectivity. Journal of the American Chemical Society. 129: 5031-44. PMID 17402733 DOI: 10.1021/Ja0676962 |
0.751 |
|
| 2007 |
Kirsch SF, Overman LE, White NS. Catalytic asymmetric synthesis of allylic aryl ethers. Organic Letters. 9: 911-3. PMID 17274626 DOI: 10.1021/Ol070110B |
0.76 |
|
| 2007 |
Overman LE, Shin Y. Enantioselective total synthesis of (+)-gliocladin C. Organic Letters. 9: 339-41. PMID 17217299 DOI: 10.1021/Ol062801Y |
0.511 |
|
| 2007 |
Govek SP, Overman LE. Synthesis of (+)-Asperazine Synfacts. 2007: 1115-1115. DOI: 10.1055/S-2007-991212 |
0.824 |
|
| 2007 |
Overman LE, Shin Y. Synthesis of (+)-Gliocladin C Synfacts. 2007: 576-576. DOI: 10.1055/S-2007-968511 |
0.394 |
|
| 2007 |
Overman L, Iimura S, Paulini R, Zakarian A. Synthesis of Guanacastepene N Synfacts. 2007: 0242-0242. DOI: 10.1055/S-2007-968196 |
0.623 |
|
| 2007 |
Govek SP, Overman LE. Total synthesis of (+)-asperazine Tetrahedron. 63: 8499-8513. DOI: 10.1016/J.Tet.2007.05.127 |
0.826 |
|
| 2007 |
Anderson CE, Kirsch SF, Overman LE, Richards CJ, Watson MP. Preparation of the cop catalysts: [(S)-COP-OAc]2, [(S)-COP-Cl]2, and (S)-COP-hfacac Organic Syntheses. 84: 148-155. DOI: 10.1002/0471264229.Os084.15 |
0.774 |
|
| 2007 |
Anderson CE, Overman LE, Richards CJ, Watson MP, White N. Preparation of (η5‐(S)‐2‐(4‐Methylethyl)‐Oxazolinylcyclopentadienyl)‐(η4‐Tetraphenylcyclo‐Butadiene)cobalt Organic Syntheses. 139-147. DOI: 10.1002/0471264229.Os084.14 |
0.802 |
|
| 2007 |
Anderson CE, Overman LE, Richards CJ, Watson MP, White N. Preparation of (η5-(S)-2-(4-methylethyl)- oxazolinylcyclopentadienyl)-(η4-tetraphenylcyclo-butadiene) cobalt (cobalt, [1,1′,1″,1‴-(η4-1,3- cyclobutadiene-1,2,3,4-tetrayl)tetrakis [benzene]] [(1,2,3,4,5-η)-1-[(4S)-4, 5-dihydro-4-(1-methylethyl)-2-oxazolyl]-2,4-cyclopentadien-1-yl]) Organic Syntheses. 84: 139-147. |
0.761 |
|
| 2006 |
Lanman BA, Overman LE. EVALUATION OF STRATEGIES FOR THE SYNTHESIS OF THE GUANIDINE HEMIAMINAL PORTION OF PALAU'AMINE. Heterocycles. 70: 557-570. PMID 19079749 DOI: 10.3987/Com-06-S(W)16 |
0.357 |
|
| 2006 |
Gergely J, Morgan JB, Overman LE. Stereocontrolled synthesis of functionalized cis-cyclopentapyrazolidines by 1,3-dipolar cycloaddition reactions of azomethine imines. The Journal of Organic Chemistry. 71: 9144-52. PMID 17109540 DOI: 10.1021/Jo061537J |
0.801 |
|
| 2006 |
Iimura S, Overman LE, Paulini R, Zakarian A. Enantioselective total synthesis of guanacastepene N using an uncommon 7-endo Heck cyclization as a pivotal step. Journal of the American Chemical Society. 128: 13095-101. PMID 17017789 DOI: 10.1021/Ja0650504 |
0.721 |
|
| 2006 |
Nilsson BL, Overman LE. Concise synthesis of guanidine-containing heterocycles using the Biginelli reaction. The Journal of Organic Chemistry. 71: 7706-14. PMID 16995677 DOI: 10.1021/Jo061199M |
0.437 |
|
| 2006 |
Garg NK, Hiebert S, Overman LE. Total synthesis of (-)-sarain A. Angewandte Chemie (International Ed. in English). 45: 2912-5. PMID 16566053 DOI: 10.1002/Anie.200600417 |
0.736 |
|
| 2006 |
Overman LE, Watson DA. Diastereoselection in the formation of contiguous quaternary carbon stereocenters by the intramolecular Heck reaction. The Journal of Organic Chemistry. 71: 2600-8. PMID 16555810 DOI: 10.1021/Jo0523363 |
0.7 |
|
| 2006 |
Overman LE, Watson DA. Diastereoselection in the formation of spirocyclic oxindoles by the intramolecular Heck reaction. The Journal of Organic Chemistry. 71: 2587-99. PMID 16555809 DOI: 10.1021/Jo052335A |
0.657 |
|
| 2006 |
Cohen F, Overman LE. Enantioselective total synthesis of batzelladine F and definition of its structure. Journal of the American Chemical Society. 128: 2604-8. PMID 16492044 DOI: 10.1021/Ja057433S |
0.579 |
|
| 2006 |
Cohen F, Overman LE. Evolution of a strategy for the synthesis of structurally complex batzelladine alkaloids. Enantioselective total synthesis of the proposed structure of batzelladine F and structural revision. Journal of the American Chemical Society. 128: 2594-603. PMID 16492043 DOI: 10.1021/Ja0574320 |
0.58 |
|
| 2006 |
Overman LE, Velthuisen EJ. Scope and facial selectivity of the Prins-pinacol synthesis of attached rings. The Journal of Organic Chemistry. 71: 1581-7. PMID 16468809 DOI: 10.1021/Jo0522862 |
0.841 |
|
| 2006 |
Overman LE, Peterson EA. Synthesis of dihydroquinolinones angularly-fused to tetrahydrobenzazepinone rings Heterocycles. 67: 585-588. DOI: 10.3987/Com-05-S(T)76 |
0.7 |
|
| 2006 |
Overman L, Garg N, Hiebert S. Synthesis of (-)-Sarain A Synfacts. 2006: 1089-1089. DOI: 10.1055/S-2006-949386 |
0.729 |
|
| 2006 |
Overman L, Cohen F. Synthesis of Batzelladine F Synfacts. 2006: 0646-0646. DOI: 10.1055/S-2006-941835 |
0.555 |
|
| 2006 |
Overman LE, Carpenter NE. The Allylic Trihaloacetimidate Rearrangement Cheminform. 37. DOI: 10.1002/0471264180.Or066.01 |
0.482 |
|
| 2005 |
Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Use of the intramolecular Heck reaction for forming congested quaternary carbon stereocenters. Stereocontrolled total synthesis of (+/-)-gelsemine. Journal of the American Chemical Society. 127: 18054-65. PMID 16366557 DOI: 10.1021/Ja055711H |
0.443 |
|
| 2005 |
Earley WG, Jacobsen JE, Madin A, Meier GP, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Aza-cope rearrangement-mannich cyclizations for the formation of complex tricyclic amines: stereocontrolled total synthesis of (+/-)-gelsemine. Journal of the American Chemical Society. 127: 18046-53. PMID 16366556 DOI: 10.1021/Ja055710P |
0.405 |
|
| 2005 |
Overman LE, Rhee YH. Total synthesis of (-)-crambidine and definition of the relative configuration of its unique tetracyclic guanidinium core. Journal of the American Chemical Society. 127: 15652-8. PMID 16262433 DOI: 10.1021/Ja055464H |
0.584 |
|
| 2005 |
Dounay AB, Overman LE, Wrobleski AD. Sequential catalytic asymmetric Heck-iminium ion cyclization: enantioselective total synthesis of the Strychnos alkaloid minfiensine. Journal of the American Chemical Society. 127: 10186-7. PMID 16028927 DOI: 10.1021/Ja0533895 |
0.457 |
|
| 2005 |
Adhikari S, Caille S, Hanbauer M, Ngo VX, Overman LE. Asymmetric construction of quaternary carbon stereocenters: high stereoselection in Mukaiyama aldol reactions of 2-siloxyindoles with chiral aldehydes. Organic Letters. 7: 2795-7. PMID 15957949 DOI: 10.1021/Ol051172+ |
0.513 |
|
| 2005 |
Kirsch SF, Overman LE. Catalytic asymmetric intramolecular aminopalladation: improved palladium(II) catalysts. The Journal of Organic Chemistry. 70: 2859-61. PMID 15787588 DOI: 10.1021/Jo047763F |
0.623 |
|
| 2005 |
Aron ZD, Overman LE. Total synthesis and properties of the crambescidin core zwitterionic acid and crambescidin 359. Journal of the American Chemical Society. 127: 3380-90. PMID 15755156 DOI: 10.1021/Ja042875+ |
0.77 |
|
| 2005 |
Kirsch SF, Overman LE. Catalytic asymmetric synthesis of chiral allylic esters. Journal of the American Chemical Society. 127: 2866-7. PMID 15740118 DOI: 10.1021/Ja0425583 |
0.654 |
|
| 2005 |
Douglas CJ, Hiebert S, Overman LE. Toward an enantioselective total synthesis of sarain A: construction of an advanced intermediate and rearrangement of the sarain A core under mild conditions. Organic Letters. 7: 933-6. PMID 15727478 DOI: 10.1021/Ol050038M |
0.676 |
|
| 2005 |
Aron ZD, Overman LE. Stereocontrolled synthesis of angularly substituted 1-azabicyclic rings by cationic 2-aza-cope rearrangements. Organic Letters. 7: 913-6. PMID 15727473 DOI: 10.1021/Ol047330Z |
0.802 |
|
| 2005 |
Anderson CE, Donde Y, Douglas CJ, Overman LE. Catalytic asymmetric synthesis of chiral allylic amines. Evaluation of ferrocenyloxazoline palladacycle catalysts and imidate motifs. The Journal of Organic Chemistry. 70: 648-57. PMID 15651813 DOI: 10.1021/Jo048490R |
0.753 |
|
| 2005 |
Prasad RS, Anderson CE, Richards CJ, Overman LE. Synthesis of tert-leucine-derived cobalt oxazoline palladacycles. Reversal of palladation diastereoselectivity and application to the asymmetric rearrangement of N-aryl trifluoroacetimidates Organometallics. 24: 77-81. DOI: 10.1021/Om0493614 |
0.657 |
|
| 2005 |
Anderson CE, Overman LE, Watson MP. Asymmetric Rearrangement of Allylic Trichloroacetimidates: Preparation of (S)‐2,2,2‐Trichloro‐N‐(1‐propylallyl)acetamide Organic Syntheses. 134-139. DOI: 10.1002/0471264229.Os082.21 |
0.712 |
|
| 2005 |
Anderson CE, Overman LE, Watson MP. Asymmetric rearrangement of allylic trichloroacetimidates: Preparation of (S)-2,2,2-trichloro-N-(1-propylallyl)acetamide Organic Syntheses. 82: 134-139. |
0.726 |
|
| 2004 |
Burke BJ, Overman LE. Enantioselective synthesis of six-membered palladacycles having metal-bound stereogenic carbons: isolation and reactivity of palladacycles containing readily accessible beta-hydrogens. Journal of the American Chemical Society. 126: 16820-33. PMID 15612721 DOI: 10.1021/Ja045047P |
0.639 |
|
| 2004 |
Kirsch SF, Overman LE, Watson MP. Monomeric cobalt oxazoline palladacycles (COP). Useful catalysts for catalytic asymmetric rearrangement of allylic trichloroacetimidates. The Journal of Organic Chemistry. 69: 8101-4. PMID 15527296 DOI: 10.1021/Jo0487092 |
0.745 |
|
| 2004 |
Huang A, Kodanko JJ, Overman LE. Asymmetric synthesis of pyrrolidinoindolines. Application for the practical total synthesis of (-)-phenserine. Journal of the American Chemical Society. 126: 14043-53. PMID 15506768 DOI: 10.1021/Ja046690E |
0.813 |
|
| 2004 |
Overman LE, Velthuisen EJ. Stereocontrolled construction of either stereoisomer of 12-oxatricyclo[6.3.1.0(2,7)]dodecanes using Prins-pinacol reactions. Organic Letters. 6: 3853-6. PMID 15469366 DOI: 10.1021/Ol0482745 |
0.82 |
|
| 2004 |
Olszewski A, Sato K, Aron ZD, Cohen F, Harris A, McDougall BR, Robinson WE, Overman LE, Weiss GA. Guanidine alkaloid analogs as inhibitors of HIV-1 Nef interactions with p53, actin, and p56lck. Proceedings of the National Academy of Sciences of the United States of America. 101: 14079-84. PMID 15371598 DOI: 10.1073/Pnas.0406040101 |
0.737 |
|
| 2004 |
Bewley CA, Ray S, Cohen F, Collins SK, Overman LE. Inhibition of HIV-1 envelope-mediated fusion by synthetic batzelladine analogues. Journal of Natural Products. 67: 1319-24. PMID 15332849 DOI: 10.1021/Np049958O |
0.502 |
|
| 2004 |
Peterson EA, Overman LE. Contiguous stereogenic quaternary carbons: a daunting challenge in natural products synthesis. Proceedings of the National Academy of Sciences of the United States of America. 101: 11943-8. PMID 15232003 DOI: 10.1073/Pnas.0402416101 |
0.621 |
|
| 2004 |
Aron ZD, Pietraszkiewicz H, Overman LE, Valeriote F, Cuevas C. Synthesis and anticancer activity of side chain analogs of the crambescidin alkaloids. Bioorganic & Medicinal Chemistry Letters. 14: 3445-9. PMID 15177450 DOI: 10.1016/J.Bmcl.2004.04.071 |
0.725 |
|
| 2004 |
Collins SK, McDonald AI, Overman LE, Rhee YH. Enantioselective total synthesis of (-)-dehydrobatzelladine C. [structure: see text]. Organic Letters. 6: 1253-5. PMID 15070310 DOI: 10.1021/Ol0498141 |
0.644 |
|
| 2004 |
Aron ZD, Overman LE. The tethered Biginelli condensation in natural product synthesis. Chemical Communications (Cambridge, England). 253-65. PMID 14740029 DOI: 10.1039/B309910E |
0.774 |
|
| 2004 |
Douglas CJ, Overman LE. Catalytic asymmetric synthesis of all-carbon quaternary stereocenters. Proceedings of the National Academy of Sciences of the United States of America. 101: 5363-7. PMID 14724294 DOI: 10.1073/Pnas.0307113101 |
0.629 |
|
| 2004 |
Burke BJ, Lebsack AD, Overman LE. Scope and limitations of the thionium ion-initiated prins-pinacol synthesis of carbocycles Synlett. 1387-1393. DOI: 10.1055/S-2004-825613 |
0.82 |
|
| 2004 |
Katz JD, Overman LE. Studies towards the total synthesis of palau'amine. Formation of 4,5-dihydropyrrole-2-carboxylate intermediates by alkene-enamide ring-closing metathesis Tetrahedron. 60: 9559-9568. DOI: 10.1016/J.Tet.2004.06.140 |
0.489 |
|
| 2004 |
Katz JD, Overman LE. Studies towards the total synthesis of palau'amine. Formation of 4,5-dihydropyrrole-2-carboxylate intermediates by alkene–enamide ring-closing metathesis Tetrahedron. 60: 9559-9568. DOI: 10.1016/j.tet.2004.06.140 |
0.402 |
|
| 2004 |
Collins SK, McDonald AI, Overman LE, Rhee YH. Enantioselective Total Synthesis of (-)-Dehydrobatzelladine C. Cheminform. 35. DOI: 10.1002/chin.200435194 |
0.59 |
|
| 2004 |
Brueggemann M, McDonald AI, Overman LE, Rosen MD, Schwink L, Scott JP. Total Synthesis of (.+-.)-Didehydrostemofoline (I) (Asparagamine A) and (.+-.)-Isodidehydrostemofoline (II). Cheminform. 35. DOI: 10.1002/chin.200417204 |
0.543 |
|
| 2003 |
Brüggemann M, McDonald AI, Overman LE, Rosen MD, Schwink L, Scott JP. Total synthesis of (+/-)-didehydrostemofoline (asparagamine A) and (+/-)-isodidehydrostemofoline. Journal of the American Chemical Society. 125: 15284-5. PMID 14664560 DOI: 10.1021/Ja0388820 |
0.675 |
|
| 2003 |
Cohen F, Collins SK, Overman LE. Assembling polycyclic bisguanidine motifs resembling batzelladine alkaloids by double tethered Biginelli condensations. Organic Letters. 5: 4485-8. PMID 14602031 DOI: 10.1021/Ol0357999 |
0.596 |
|
| 2003 |
Anderson CE, Overman LE. Catalytic asymmetric rearrangement of allylic trichloroacetimidates. A practical method for preparing allylic amines and congeners of high enantiomeric purity. Journal of the American Chemical Society. 125: 12412-3. PMID 14531676 DOI: 10.1021/Ja037086R |
0.669 |
|
| 2003 |
Overman LE, Pennington LD. Strategic use of pinacol-terminated Prins cyclizations in target-oriented total synthesis. The Journal of Organic Chemistry. 68: 7143-57. PMID 12968864 DOI: 10.1021/Jo034982C |
0.776 |
|
| 2003 |
Dounay AB, Overman LE. The asymmetric intramolecular Heck reaction in natural product total synthesis. Chemical Reviews. 103: 2945-64. PMID 12914487 DOI: 10.1021/Cr020039H |
0.477 |
|
| 2003 |
Kodanko JJ, Overman LE. Enantioselective total syntheses of the cyclotryptamine alkaloids hodgkinsine and hodgkinsine B. Angewandte Chemie (International Ed. in English). 42: 2528-31. PMID 12800178 DOI: 10.1002/Anie.200351261 |
0.683 |
|
| 2003 |
Overman LE, Peterson EA. Enantioselective total synthesis of the cyclotryptamine alkaloid idiospermuline. Angewandte Chemie (International Ed. in English). 42: 2525-8. PMID 12800177 DOI: 10.1002/Anie.200351260 |
0.697 |
|
| 2003 |
Dounay AB, Hatanaka K, Kodanko JJ, Oestreich M, Overman LE, Pfeifer LA, Weiss MM. Catalytic asymmetric synthesis of quaternary carbons bearing two aryl substituents. Enantioselective synthesis of 3-alkyl-3-aryl oxindoles by catalytic asymmetric intramolecular heck reactions. Journal of the American Chemical Society. 125: 6261-71. PMID 12785859 DOI: 10.1021/Ja034525D |
0.798 |
|
| 2003 |
Corminboeuf O, Overman LE, Pennington LD. Enantioselective total synthesis of briarellins E and F: the first total syntheses of briarellin diterpenes. Journal of the American Chemical Society. 125: 6650-2. PMID 12769572 DOI: 10.1021/Ja035445C |
0.799 |
|
| 2003 |
Overman LE, Owen CE, Pavan MM, Richards CJ. Catalytic asymmetric rearrangement of allylic N-aryl trifluoroacetimidates. A useful method for transforming prochiral allylic alcohols to chiral allylic amines. Organic Letters. 5: 1809-12. PMID 12762658 DOI: 10.1021/Ol0271786 |
0.481 |
|
| 2003 |
Corminboeuf O, Overman LE, Pennington LD. Total synthesis of the reputed structure of alcyonin and reassignment of its structure. Organic Letters. 5: 1543-6. PMID 12713319 DOI: 10.1021/Ol034384K |
0.706 |
|
| 2003 |
Overman LE, Peterson EA. Enantioselective synthesis of (-)-idiospermuline Tetrahedron. 59: 6905-6919. DOI: 10.1016/S0040-4020(03)00855-X |
0.706 |
|
| 2003 |
Overman LE, Rishton GM. Stereocontrolled Preparation of 3‐Acyltetrahydrofurans from Acid‐Promoted Rearrangements of Allylic Ketals: (2S,3S)‐3‐Acetyl‐8‐Carboethoxy‐2,3‐Dimethyl‐1‐Oxa‐8‐Azaspiro[4.5]Decane Organic Syntheses. 63-63. DOI: 10.1002/0471264180.Os071.08 |
0.41 |
|
| 2003 |
Overman LE, Rishton GM. 3‐(S)‐[(tert‐Butyldiphenylsilyl)Oxy]‐2‐Butanone Organic Syntheses. 56-56. DOI: 10.1002/0471264180.Os071.07 |
0.373 |
|
| 2003 |
Arnold H, Overman LE, Sharp MJ, Witschel MC. (E)‐1‐Benzyl‐3‐(1‐Iodoethylidene)Piperidine: Nucleophile‐Promoted Alkyne‐Iminium Ion Cyclizations Organic Syntheses. 111-111. DOI: 10.1002/0471264180.Os070.13 |
0.406 |
|
| 2003 |
Overman LE, Flann CJ, Malone TC. Regioselective Synthesis of Tetrahydropyridines: 1-(4-Methoxyphenyl)-1,2,5,6-tetrahydropyridine Organic Syntheses. 188-188. DOI: 10.1002/0471264180.Os068.23 |
0.458 |
|
| 2003 |
Overman LE, Brown MJ, McCann SF. (Z)‐4‐(Trimethylsilyl)‐3‐Buten‐1‐ol Organic Syntheses. 182-182. DOI: 10.1002/0471264180.Os068.22 |
0.353 |
|
| 2003 |
Jessup PJ, Petty CB, Roos J, Overman LE. 1‐N‐Acylamino‐1,3‐dienes from 2,4‐Pentadienoic Acids by the Curtius Rearrangement: Benzyl trans‐1,3‐butadiene‐1‐carbamate Organic Syntheses. 1-1. DOI: 10.1002/0471264180.Os059.01 |
0.365 |
|
| 2003 |
Clizbe LA, Overman LE. Allylically Transposed Amines from Allylic Alcohols: 3,7‐Dimethyl‐1,6‐Octadien‐3‐Amine Organic Syntheses. 4-4. DOI: 10.1002/0471264180.Os058.02 |
0.323 |
|
| 2002 |
Bélanger G, Hong FT, Overman LE, Rogers BN, Tellew JE, Trenkle WC. Stereocontrolled synthesis of triazacyclopenta[cd]pentalenes by intramolecular 1,3-dipolar cycloaddition reactions of azomethine imines. The Journal of Organic Chemistry. 67: 7880-3. PMID 12398520 DOI: 10.1021/Jo026282Y |
0.824 |
|
| 2002 |
Overman LE, Owen CE, Zipp GG. Diastereoselective lithiation of (eta6-arene)dicarbonyltriphenylphosphane chromium(0) oxazoline complexes--direct preparation of enantiopure complexes having planar chiral fragments of either configuration. Angewandte Chemie (International Ed. in English). 41: 3884-7. PMID 12386879 DOI: 10.1002/1521-3773(20021018)41:20<3884::Aid-Anie3884>3.0.Co;2-0 |
0.802 |
|
| 2002 |
Overman LE, Wolfe JP. New cationic olefin cyclization-pinacol reactions. Ring-expanding cyclopentane annulations that directly install useful functionality in the cyclopentane ring. The Journal of Organic Chemistry. 67: 6421-9. PMID 12201763 DOI: 10.1021/Jo025927R |
0.663 |
|
| 2002 |
Lebsack AD, Link JT, Overman LE, Stearns BA. Enantioselective total synthesis of quadrigemine C and psycholeine. Journal of the American Chemical Society. 124: 9008-9. PMID 12148978 DOI: 10.1021/Ja0267425 |
0.849 |
|
| 2002 |
Hynes J, Nasser T, Overman LE, Watson DA. Preparation of alpha-sulfenyl enones by thermal fragmentation of beta-sulfenyl enol triflates. Organic Letters. 4: 929-31. PMID 11893188 DOI: 10.1021/Ol017303Y |
0.736 |
|
| 2002 |
Kamenecka TM, Overman LE, Ly Sakata SK. Construction of substituted cyclohexanones by reductive cyclization of 7-oxo-2,8-alkadienyl esters. Organic Letters. 4: 79-82. PMID 11772095 DOI: 10.1021/Ol0169325 |
0.495 |
|
| 2002 |
Overman LE, Remarchuk TP. Catalytic asymmetric intramolecular aminopalladation: enantioselective synthesis of vinyl-substituted 2-oxazolidinones, 2-imidazolidinones, and 2-pyrrolidinones. Journal of the American Chemical Society. 124: 12-3. PMID 11772049 DOI: 10.1021/Ja017198N |
0.848 |
|
| 2002 |
Berger D, Overman L. Preparation of Seven-Membered Cyclic Ethers Containing Halogenated Side Chains by Acetal-Alkene Cyclizations Synlett. 1992: 811-813. DOI: 10.1055/S-1992-21501 |
0.423 |
|
| 2002 |
Gahman TC, Overman LE. Stereoselective synthesis of carbocyclic ring systems by pinacol-terminated Prins cyclizations Tetrahedron. 58: 6473-6483. DOI: 10.1016/S0040-4020(02)00658-0 |
0.462 |
|
| 2001 |
Oestreich M, Dennison PR, Kodanko JJ, Overman LE. Thwarting β-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction. Angewandte Chemie (International Ed. in English). 40: 1439-1442. PMID 29712379 DOI: 10.1002/1521-3773(20010417)40:8<1439::Aid-Anie1439>3.0.Co;2-F |
0.732 |
|
| 2001 |
Cohen F, Overman LE. Enantioselective total synthesis of batzelladine F: structural revision and stereochemical definition. Journal of the American Chemical Society. 123: 10782-3. PMID 11674029 DOI: 10.1021/Ja017067M |
0.587 |
|
| 2001 |
Govek SP, Overman LE. Total synthesis of asperazine. Journal of the American Chemical Society. 123: 9468-9. PMID 11562240 DOI: 10.1021/ja016616l |
0.811 |
|
| 2001 |
Overman LE, Paone DV. Enantioselective total syntheses of ditryptophenaline and ent-WIN 64821. Journal of the American Chemical Society. 123: 9465-7. PMID 11562239 DOI: 10.1021/Ja0166141 |
0.475 |
|
| 2001 |
MacMillan DW, Overman LE, Pennington LD. A general strategy for the synthesis of cladiellin diterpenes: enantioselective total syntheses of 6-acetoxycladiell-7(16),11-dien-3-ol (deacetoxyalcyonin acetate), cladiell-11-ene-3,6,7-triol, sclerophytin A, and the initially purported structure of sclerophytin A. Journal of the American Chemical Society. 123: 9033-44. PMID 11552811 DOI: 10.1021/Ja016351A |
0.856 |
|
| 2001 |
Lebsack AD, Overman LE, Valentekovich RJ. Enantioselective total synthesis of shahamin K. Journal of the American Chemical Society. 123: 4851-2. PMID 11457302 DOI: 10.1021/Ja015802O |
0.774 |
|
| 2001 |
Gallou F, MacMillan DW, Overman LE, Paquette LA, Pennington LD, Yang J. Enantioselective syntheses of authentic sclerophytin A, sclerophytin B, and cladiell-11-ene-3,6,7-triol. Organic Letters. 3: 135-7. PMID 11429857 DOI: 10.1021/Ol000345M |
0.805 |
|
| 2001 |
Kamatani A, Overman LE. A new asymmetric synthesis of trans-hydroisoquinolones. Organic Letters. 3: 1229-32. PMID 11348201 DOI: 10.1021/Ol015696V |
0.49 |
|
| 2001 |
Cohen F, MacMillan DW, Overman LE, Romero A. Stereoselection in the Prins-pinacol synthesis of acyltetrahydrofurans. Organic Letters. 3: 1225-8. PMID 11348200 DOI: 10.1021/Ol0157003 |
0.785 |
|
| 2001 |
Overman LE, Wolfe JP. Synthesis of polycyclic guanidines by cyclocondensation reactions of N-amidinyliminium ions. The Journal of Organic Chemistry. 66: 3167-75. PMID 11325284 DOI: 10.1021/Jo0100998 |
0.61 |
|
| 2001 |
Oestreich M, Dennison PR, Kodanko JJ, Overman LE. Thwarting beta-Hydride Elimination: Capture of the Alkylpalladium Intermediate of an Asymmetric Intramolecular Heck Reaction This research was supported by the National Institutes of Health (grant GM-12389). M.O. thanks the Deutsche Forschungsgemeinschaft (DFG) for an Emmy Noether fellowship (Oe 249/1-1). NMR and mass spectra were determined at the University of California, Irvine with instruments purchased with the assistance of the NSF and NIH shared instrumentation programs. We are grateful to Dr. Joseph W. Ziller and Dr. John Greaves for their assistance with X-ray structure and mass spectrometric analyses. Angewandte Chemie (International Ed. in English). 40: 1439-1442. PMID 11317296 DOI: 10.1002/1521-3773(20010417)40:8<1439::AID-ANIE1439>3.0.CO;2-F |
0.664 |
|
| 2001 |
O'Connor SJ, Overman LE, Rucker PV. Use of sequential intramolecular heck cyclizations for preparing bicyclo[3.2.1]octane fragments of tetracyclic stemodane and stemarane diterpenes Synlett. 1009-1012. DOI: 10.1055/S-2001-14648 |
0.404 |
|
| 2001 |
Gasparski CM, Herrinton PM, Overman LE, Wolfe JP. ChemInform Abstract: Synthesis of 3-Acyltetrahydrofurans from Formaldehyde Acetals of Allylic Diols. Cheminform. 32: no-no. DOI: 10.1002/chin.200110108 |
0.658 |
|
| 2001 |
Ashimori A, Overman LE. ChemInform Abstract: Catalytic Asymmetric Synthesis of Quaternary Carbon Centers by Intramolecular Heck Reaction: Synthetic Developments and Mechanistic Studies Cheminform. 32: no-no. DOI: 10.1002/chin.200105290 |
0.422 |
|
| 2001 |
Ponce AM, Overman LE. ChemInform Abstract: A New Method for Stereocontrolled Synthesis of Substituted Tetrahydrothiophenes. Cheminform. 32: no-no. DOI: 10.1002/chin.200101041 |
0.332 |
|
| 2001 |
Oestreich M, Dennison PR, Kodanko JJ, Overman LE. Vereitelteβ-Hydrideliminierung: Abfangen der Alkylpalladiumzwischenstufe einer asymmetrischen intramolekularen Heck-Reaktion Angewandte Chemie. 113: 1485-1489. DOI: 10.1002/1521-3757(20010417)113:8<1485::Aid-Ange1485>3.0.Co;2-F |
0.692 |
|
| 2000 |
Overman LE, Rosen MD. Total Synthesis of (-)-Spirotryprostatin B and Three Stereoisomers We thank NIH NIGMS (GM-30859) for financial support, Prof. A. J. Shaka and N. D. Taylor for DPFGSE experiments, Prof. H. Osada for providing spectral data for natural 1, and Prof. R. M. Williams and P. R. Sebahar for providing spectral data and a sample of synthetic ent-21. We are also grateful to Prof. R. M. Williams and Prof. S. J. Danishefsky for open exchange of information prior to publication. NMR and mass spectra were determined at UC Irvine with instruments purchased with the assistance of the NSF and NIH shared instrumentation programs. Angewandte Chemie (International Ed. in English). 39: 4596-4599. PMID 11169682 DOI: 10.1002/1521-3773(20001215)39:24<4596::Aid-Anie4596>3.0.Co;2-F |
0.531 |
|
| 2000 |
Hoyt SB, Overman LE. Investigation of a dialkylation approach for enantioselective construction of vicinal quaternary stereocenters. Organic Letters. 2: 3241-4. PMID 11009391 DOI: 10.1021/Ol006494M |
0.331 |
|
| 2000 |
Overman LE, Pennington LD. Total synthesis of the supposed structure of (-)-sclerophytin A and an improved route to (-)-7-deacetoxyalcyonin acetate. Organic Letters. 2: 2683-6. PMID 10990427 DOI: 10.1021/Ol006236P |
0.775 |
|
| 2000 |
Hanaki N, Link JT, MacMillan DW, Overman LE, Trankle WG, Wurster JA. Stereoselection in the prins-pinacol synthesis of 2,2-disubstituted 4-acyltetrahydrofurans. Enantioselective synthesis of (-)-citreoviral. Organic Letters. 2: 223-6. PMID 10814287 DOI: 10.1021/Ol991315Q |
0.748 |
|
| 2000 |
Overman LE, Larrow JF, Stearns BA, Vance JM. Enantioselective Construction of Vicinal Stereogenic Quaternary Centers by Dialkylation: Practical Total Syntheses of (+)- and meso-Chimonanthine. Angewandte Chemie (International Ed. in English). 39: 213-215. PMID 10649379 DOI: 10.1002/(Sici)1521-3773(20000103)39:1<213::Aid-Anie213>3.0.Co;2-Z |
0.797 |
|
| 2000 |
Ashimori A, Overman LE. Catalytic asymmetric synthesis of quaternary carbon centers by intramolecular Heck reaction: Synthetic developments and mechanistic studies Yuki Gosei Kagaku Kyokaishi/Journal of Synthetic Organic Chemistry. 58: 718-727. DOI: 10.5059/Yukigoseikyokaishi.58.718 |
0.454 |
|
| 2000 |
Overman LE, Rucker PV. Investigations directed at the total synthesis of ouabain. Lessons learned from degradation studies Heterocycles. 52: 1297-1314. DOI: 10.3987/Com-99-S142 |
0.306 |
|
| 2000 |
Overman LE, Pennington LD. A new strategy for synthesis of attached rings Canadian Journal of Chemistry. 78: 732-738. DOI: 10.1139/V00-022 |
0.779 |
|
| 2000 |
Ponce AM, Overman LE. A new method for stereocontrolled synthesis of substituted tetrahydrothiophenes Journal of the American Chemical Society. 122: 8672-8676. DOI: 10.1021/Ja001975M |
0.497 |
|
| 2000 |
Coffey DS, Overman LE, Stappenbeck F. Enantioselective total syntheses of 13,14,15-isocrambescidin 800 and 13,14,15-isocrambescidin 657 Journal of the American Chemical Society. 122: 4904-4914. DOI: 10.1021/ja000235a |
0.375 |
|
| 2000 |
Coffey DS, McDonald AI, Overman LE, Rabinowitz MH, Renhowe PA. A practical entry to the crambescidin family of guanidine alkaloids. Enantioselective total syntheses of ptilomycalin A, crambescidin 657 and its methyl ester (neofolitispates 2), and crambescidin 800 Journal of the American Chemical Society. 122: 4893-4903. DOI: 10.1021/Ja000234I |
0.489 |
|
| 2000 |
Gasparski CM, Herrinton PM, Overman LE, Wolfe JP. Synthesis of 3-acyltetrahydrofurans from formaldehyde acetals of allylic diols Tetrahedron Letters. 41: 9431-9435. DOI: 10.1016/S0040-4039(00)01571-9 |
0.666 |
|
| 2000 |
Overman LE, Pennington LD. ChemInform Abstract: A New Strategy for Synthesis of Attached Rings. Cheminform. 31: no-no. DOI: 10.1002/chin.200049043 |
0.748 |
|
| 2000 |
Coffey DS, Overman LE, Stappenbeck F. ChemInform Abstract: Enantioselective Total Syntheses of 13,14,15-Isocrambescidin 800 and 13,14,15-Isocrambescidin 657. Cheminform. 31: no-no. DOI: 10.1002/chin.200037222 |
0.362 |
|
| 2000 |
Overman LE, Rosen MD. Totalsynthese von (−)-Spirotryprostatin B und drei Stereoisomeren Angewandte Chemie. 112: 4768-4771. DOI: 10.1002/1521-3757(20001215)112:24<4768::Aid-Ange4768>3.0.Co;2-7 |
0.517 |
|
| 1999 |
McDonald AI, Overman LE. Tuning Stereoselection in Tethered Biginelli Condensations. Synthesis of cis- or trans-1-Oxo- and 1-Iminohexahydropyrrolo[1,2-c]pyrimidines. The Journal of Organic Chemistry. 64: 1520-1528. PMID 11674214 DOI: 10.1021/Jo981972G |
0.385 |
|
| 1999 |
Franklin AS, Ly SK, Mackin GH, Overman LE, Shaka AJ. Application of the Tethered Biginelli Reaction for Enantioselective Synthesis of Batzelladine Alkaloids. Absolute Configuration of the Tricyclic Guanidine Portion of Batzelladine B. The Journal of Organic Chemistry. 64: 1512-1519. PMID 11674213 DOI: 10.1021/Jo981971O |
0.422 |
|
| 1999 |
Cohen F, Overman LE, Sakata SK. Asymmetric total synthesis of batzelladine D. Organic Letters. 1: 2169-72. PMID 10836070 DOI: 10.1021/Ol991269U |
0.682 |
|
| 1999 |
Madin A, O'Donnell CJ, Oh T, Old DW, Overman LE, Sharp MJ. Total Synthesis of (+/-)-Gelsemine. Angewandte Chemie (International Ed. in English). 38: 2934-2936. PMID 10540398 DOI: 10.1002/(Sici)1521-3773(19991004)38:19<2934::Aid-Anie2934>3.0.Co;2-L |
0.519 |
|
| 1999 |
Kamatani A, Overman LE. A Suzuki coupling method for directly introducing a protected β- aminoethyl group into arenes and alkenes. Convenient synthesis of phenethyl and homoallylic amines Journal of Organic Chemistry. 64: 8743-8744. DOI: 10.1021/Jo991064Z |
0.39 |
|
| 1999 |
Bogenstätter M, Limberg A, Overman LE, Tomasi AL. Enantioselective total synthesis of the kinesin motor protein inhibitor adociasulfate 1 [12] Journal of the American Chemical Society. 121: 12206-12207. DOI: 10.1021/ja9934091 |
0.789 |
|
| 1999 |
Overman LE, Paone DV, Stearns BA. Direct stereo- and enantiocontrolled synthesis of vicinal stereogenic quaternary carbon centers. Total syntheses of meso- and (-)-chimonanthine and (+)-calycanthine [4] Journal of the American Chemical Society. 121: 7702-7703. DOI: 10.1021/Ja991714G |
0.8 |
|
| 1999 |
Coffey DS, McDonald AI, Overman LE, Stappenbeck F. Enantioselective total synthesis of 13,14,15-isocrambescidin 800 [5] Journal of the American Chemical Society. 121: 6944-6945. DOI: 10.1021/ja990992c |
0.42 |
|
| 1999 |
Fox ME, Li C, Marino JP, Overman LE. Enantiodivergent total syntheses of (+)- and (-)-scopadulcic acid A Journal of the American Chemical Society. 121: 5467-5480. DOI: 10.1021/Ja990404V |
0.509 |
|
| 1999 |
Cloninger MJ, Overman LE. Stereocontrolled synthesis of trisubstituted tetrahydropyrans [3] Journal of the American Chemical Society. 121: 1092-1093. DOI: 10.1021/Ja9838007 |
0.846 |
|
| 1999 |
Donde Y, Overman LE. High enantioselection in the rearrangement of allylic imidates with ferrocenyl oxazoline catalysts Journal of the American Chemical Society. 121: 2933-2934. DOI: 10.1021/Ja983263Q |
0.354 |
|
| 1999 |
Brosius AD, Overman LE, Schwink L. Total synthesis of (+)-aloperine. Use of a nitrogen-bound silicon tether in an intramolecular Dieis-Alder reaction Journal of the American Chemical Society. 121: 700-709. DOI: 10.1021/ja983013+ |
0.339 |
|
| 1999 |
Jaroch S, Matsuoka RT, Overman LE. Studies towards a total synthesis of Sarains A-C. Stereospecific condensation of α,β-unsaturated esters with the phenyl oxazoline derivative of threonine Tetrahedron Letters. 40: 1273-1276. DOI: 10.1016/S0040-4039(98)02639-2 |
0.374 |
|
| 1999 |
Keith Hollis T, Overman LE. Palladium catalyzed enantioselective rearrangement of allylic imidates to allylic amides Journal of Organometallic Chemistry. 576: 290-299. DOI: 10.1016/S0022-328X(98)01065-1 |
0.376 |
|
| 1999 |
Iserloh U, Ashimori A, Curran DP, Bachand B, Overman LE, Poon DJ, Calter MA, Govek SP, Matsuura T. Catalytic asymmetric synthesis of quaternary carbon centers: Investigation of intramolecular Heck reactions and the application to calabar alkaloid synthesis Chemtracts. 12: 289-296. |
0.852 |
|
| 1998 |
Ando K, Condroski KR, Houk KN, Wu YD, Ly SK, Overman LE. Stereoselectivities of Nucleophilic Additions to Cycloheptanones. Experimental and Theoretical Studies and General Purpose Force Field for the Prediction of Nucleophilic Addition Stereoselectivities Journal of Organic Chemistry. 63: 3196-3203. DOI: 10.1021/Jo971627B |
0.333 |
|
| 1998 |
Matsuura T, Overman LE, Poon DJ. Catalytic asymmetric synthesis of either enantiomer of the calabar alkaloids physostigmine and physovenine Journal of the American Chemical Society. 120: 6500-6503. DOI: 10.1021/ja980788+ |
0.413 |
|
| 1998 |
Ashimori A, Bachand B, Calter MA, Govek SP, Overman LE, Poon DJ. Catalytic asymmetric synthesis of quaternary carbon centers. Exploratory studies of intramolecular Heck reactions of (Z)-α,β-unsaturated anilides and mechanistic investigations of asymmetric Heck reactions proceeding via neutral intermediates Journal of the American Chemical Society. 120: 6488-6499. DOI: 10.1021/ja980787h |
0.828 |
|
| 1998 |
Ashimori A, Bachand B, Overman LE, Poon DJ. Catalytic asymmetric synthesis of quaternary carbon centers. Exploratory investigations of intramolecular heck reactions of (E)-α,β-unsaturated 2-haloanilides and analogues to form enantioenriched spirocyclic products Journal of the American Chemical Society. 120: 6477-6487. DOI: 10.1021/Ja980786P |
0.469 |
|
| 1998 |
Overman LE, Tomasi AL. Enantioselective total synthesis of hispidospermidin [13] Journal of the American Chemical Society. 120: 4039-4040. DOI: 10.1021/Ja974361Z |
0.847 |
|
| 1998 |
Cohen F, Overman LE. Planar-chiral cyclopalladated ferrocenyl amines and imines as enantioselective catalysts for allylic imidate rearrangements Tetrahedron Asymmetry. 9: 3213-3222. DOI: 10.1016/S0957-4166(98)00341-3 |
0.641 |
|
| 1998 |
Hynes J, Overman LE, Nasser T, Rucker PV. Intramolecular Heck cyclization of α-sulfenyl enol triflates. Asymmetric synthesis of a pentacyclic cardenolide precursor having functionality at C-11 Tetrahedron Letters. 39: 4647-4650. DOI: 10.1016/S0040-4039(98)00860-0 |
0.459 |
|
| 1998 |
Overman LE, Rucker PV. Enantioselective synthesis of cardenolide precursors using an intramolecular Heck reaction Tetrahedron Letters. 39: 4643-4646. DOI: 10.1016/S0040-4039(98)00859-4 |
0.444 |
|
| 1997 |
Overman LE, Zipp GG. Allylic Transposition of Alcohol and Amine Functionality by Thermal or Palladium(II)-Catalyzed Rearrangements of Allylic N-Benzoylbenzimidates. The Journal of Organic Chemistry. 62: 2288-2291. PMID 11671546 DOI: 10.1021/Jo962129Q |
0.762 |
|
| 1997 |
Brosius AD, Overman LE. Aloperine: Stereocontrolled Synthesis of Two Stereoisomers and Determination of Absolute Configuration. The Journal of Organic Chemistry. 62: 440-441. PMID 11671426 DOI: 10.1021/Jo9621231 |
0.465 |
|
| 1997 |
Abelman MM, Kado N, Overman LE, Sarkar AK. Synthesis of a phenolic analog of aphidicolin. Diminished stereoselection in intramolecular 6-exo Heck reactions of substrates having a hydrocarbon tether Synlett. 1469-1471. DOI: 10.1055/S-1997-1066 |
0.503 |
|
| 1997 |
Metais E, Overman LE, Rodriguez MI, Stearns BA. Halide-terminated N-acyliminium ion-alkyne cyclizations: A new construction of carbacephem antibiotics Journal of Organic Chemistry. 62: 9210-9216. DOI: 10.1021/Jo971433W |
0.778 |
|
| 1997 |
Ando S, Minor KP, Overman LE. Ring-Enlarging Cyclohexane Annulations Journal of Organic Chemistry. 62: 6379-6387. DOI: 10.1021/Jo970399I |
0.413 |
|
| 1997 |
Calter M, Hollis TK, Overman LE, Ziller J, Zipp GG. First Enantioselective Catalyst for the Rearrangement of Allylic Imidates to Allylic Amides Journal of Organic Chemistry. 62: 1449-1456. DOI: 10.1021/Jo962090P |
0.811 |
|
| 1997 |
Overman LE, Ricca DJ, Tran VD. Total synthesis of (±)-scopadulcic acid B Journal of the American Chemical Society. 119: 12031-12040. DOI: 10.1021/Ja972427K |
0.475 |
|
| 1997 |
Overman LE, Rogers BN, Tellew JE, Trenkle WC. Stereocontrolled synthesis of the tetracyclic core of the bisguanidine alkaloids palau'amine and styloguanidine [4] Journal of the American Chemical Society. 119: 7159-7160. DOI: 10.1021/Ja9712985 |
0.815 |
|
| 1997 |
Berger D, Overman LE, Renhowe PA. Total synthesis of (+)-isolaurepinnacin. Use of acetal-alkene cyclizations to prepare highly functionalized seven-membered cyclic ethers Journal of the American Chemical Society. 119: 2446-2452. DOI: 10.1021/Ja964080B |
0.536 |
|
| 1997 |
Hollis TK, Overman LE. Cyclopalladated ferrocenyl amines as enantioselective catalysts for the rearrangement of allylic imidates to allylic amides Tetrahedron Letters. 38: 8837-8840. DOI: 10.1016/S0040-4039(97)10385-9 |
0.688 |
|
| 1997 |
Joe D, Overman LE. An unexpected product arising from metal alkylidene mediated ring-closing diene metathesis Tetrahedron Letters. 38: 8635-8638. DOI: 10.1016/S0040-4039(97)10373-2 |
0.38 |
|
| 1997 |
Hong CY, Overman LE, Romero A. Pyridinomorphinans: Asymmetric synthesis of either enantiomer and opioid receptor binding selectivity Tetrahedron Letters. 38: 8439-8442. DOI: 10.1016/S0040-4039(97)10274-X |
0.36 |
|
| 1997 |
Minor KP, Overman LE. Prins-pinacol spiroannulations Tetrahedron. 53: 8927-8940. DOI: 10.1016/S0040-4020(97)90401-4 |
0.426 |
|
| 1997 |
Overman LE, Trenkle WC. Controlling stereoselection in aza-Cope-Mannich reactions Israel Journal of Chemistry. 37: 23-30. DOI: 10.1002/Ijch.199700005 |
0.797 |
|
| 1997 |
Overman LE, Poon DJ. Asymmetric Heck Reactions via Neutral Intermediates: Enhanced Enantioselectivity with Halide Additives Gives Mechanistic Insights Angewandte Chemie (International Edition in English). 36: 518-521. DOI: 10.1002/Anie.199705181 |
0.434 |
|
| 1996 |
Franklin AS, Overman LE. Total Syntheses of Pumiliotoxin A and Allopumiliotoxin Alkaloids. Interplay of Pharmacologically Active Natural Products and New Synthetic Methods and Strategies. Chemical Reviews. 96: 505-522. PMID 11848762 DOI: 10.1021/Cr950021P |
0.332 |
|
| 1996 |
Overman LE, Tellew JE. Synthesis of 2-Azatricyclo[5.2.1.0(4,10)]decanes and 2,5-Diazatricyclo[5.2.1.0(4,10)]decanes by Intramolecular Azomethine Ylide Cycloadditions. The Journal of Organic Chemistry. 61: 8338-8340. PMID 11667832 DOI: 10.1021/Jo961341R |
0.535 |
|
| 1996 |
Deng W, Jensen MS, Overman LE, Rucker PV, Vionnet JP. A Strategy for Total Synthesis of Complex Cardenolides. The Journal of Organic Chemistry. 61: 6760-6761. PMID 11667560 DOI: 10.1021/Jo961209R |
0.801 |
|
| 1996 |
Murata Y, Overman LE. Aprotic chloride and bromide-promoted alkyne-iminium ion cyclizations Heterocycles. 42: 549-552. DOI: 10.3987/Com-95-S96 |
0.306 |
|
| 1996 |
Link JT, Overman LE. Stereocontrolled total syntheses of meso-chimonanthine and meso-calycanthine via a novel samarium mediated reductive dialkylation Journal of the American Chemical Society. 118: 8166-8167. DOI: 10.1021/Ja961757M |
0.429 |
|
| 1996 |
Lin NH, Overman LE, Rabinowitz MH, Robinson LA, Sharp MJ, Zablocki J. Efficient total syntheses of pumiliotoxins A and B. Applications of iodide-promoted iminium ion-alkyne cyclizations in alkaloid construction Journal of the American Chemical Society. 118: 9062-9072. DOI: 10.1021/Ja961641Q |
0.514 |
|
| 1996 |
Caderas R, Lett R, Overman LE, Rabinowitz MH, Robinson LA, Sharp MJ, Zablocki J. Enantioselective total syntheses of allopumiliotoxins 267A, 323B', and 339A. Application of iodide-promoted iminium ion-alkyne cyclizations for forming allopumiliotoxin A alkaloids Journal of the American Chemical Society. 118: 9073-9082. DOI: 10.1021/Ja961640Y |
0.498 |
|
| 1996 |
Overman LE, Tellew JE. Synthesis of 2-azatricyclo[5.2.1.04,10]decanes and 2,5-diazatricyclo[5.2.1.04,10]decanes by intramolecular azomethine ylide cycloadditions Journal of Organic Chemistry. 61: 8338-8340. |
0.442 |
|
| 1995 |
MacMillan DWC, Overman LE. Enantioselective Total Synthesis of (-)-7-Deacetoxyalcyonin Acetate. First Synthesis of a Eunicellin Diterpene Journal of the American Chemical Society. 117: 10391-10392. DOI: 10.1021/Ja00146A028 |
0.521 |
|
| 1995 |
Lögers M, Overman LE, Welmaker GS. Mannich biscyclizations. Total synthesis of (-)-ajmalicine Journal of the American Chemical Society. 117: 9139-9150. DOI: 10.1021/Ja00141A004 |
0.805 |
|
| 1995 |
Bratz M, Bullock WH, Overman LE, Takemoto T. Total Synthesis of (+)-Laurencin. Use of Acetal-Vinyl Sulfide Cyclizations for Forming Highly Functionalized Eight-Membered Cyclic Ethers Journal of the American Chemical Society. 117: 5958-5966. DOI: 10.1021/Ja00127A008 |
0.486 |
|
| 1995 |
Knight SD, Overman LE, Pairaudeau G. Asymmetric total syntheses of (-)- and (+)-strychnine and the Wieland-Gumlich aldehyde Journal of the American Chemical Society. 117: 5776-5788. DOI: 10.1021/Ja00126A017 |
0.522 |
|
| 1995 |
Overman LE, Rabinowitz MH, Renhowe PA. Enantioselective Total Synthesis of (-)-Ptilomycalin A Journal of the American Chemical Society. 117: 2657-2658. DOI: 10.1021/Ja00114A034 |
0.516 |
|
| 1995 |
Hayashi T, Sugimoto T, Takewaki N, Takeguchi N, Tran VD, O'Connor SJ, Rucker PV, Overman LE. Silyl ethers of cycloheptene, novel proton pump inhibitors obtained during the total synthesis of the scopadulcic acids Bioorganic & Medicinal Chemistry Letters. 5: 2943-2946. DOI: 10.1016/0960-894X(95)00493-8 |
0.353 |
|
| 1994 |
Overman LE. Application of intramolecular Heck reactions for forming congested quaternary carbon centers in complex molecule total synthesis Pure and Applied Chemistry. 66: 1423-1430. DOI: 10.1351/Pac199466071423 |
0.462 |
|
| 1994 |
Overman LE, Renhowe PA. Regioselective Opening of Terminal Epoxides with 2-(Trialkylsilyl)allyl Organometallic Reagents The Journal of Organic Chemistry. 59: 4138-4142. DOI: 10.1021/Jo00094A026 |
0.424 |
|
| 1994 |
Leotta GJ, Overman LE, Welmaker GS. A Convenient Method for the Preparation of 3-Substituted Glutarate Diesters Journal of Organic Chemistry. 59: 1946-1946. DOI: 10.1021/Jo00086A065 |
0.354 |
|
| 1994 |
Deng W, Overman LE. Enantioselective total synthesis of either enantiomer of the antifungal antibiotic preussin (L-657,398) from (S)-phenylalanine Journal of the American Chemical Society. 116: 11241-11250. DOI: 10.1021/Ja00104A005 |
0.494 |
|
| 1994 |
Kamenecka TM, Overman LE. An enantioselective approach to the synthesis of manzamine A Tetrahedron Letters. 35: 4279-4282. DOI: 10.1016/S0040-4039(00)73333-8 |
0.474 |
|
| 1994 |
Hong CY, Overman LE. Preparation of opium alkaloids by palladium catalyzed bis-cyclizations. Formal total synthesis of morphine Tetrahedron Letters. 35: 3453-3456. DOI: 10.1016/S0040-4039(00)73208-4 |
0.535 |
|
| 1994 |
Laschat S, Narjes F, Overman LE. Application of intramolecular Heck reactions to the preparation of steroid and terpene intermediates having cis A-B ring fusions. Model studies for the total synthesis of complex cardenolides. Tetrahedron. 50: 347-358. DOI: 10.1016/S0040-4020(01)80759-6 |
0.497 |
|
| 1993 |
Ashimori A, Matsuura T, Overman LE, Poon DJ. Catalytic asymmetric synthesis of either enantiomer of physostigmine. Formation of quaternary carbon centers with high enantioselection by intramolecular Heck reactions of (Z)-2-butenanilides The Journal of Organic Chemistry. 58: 6949-6951. DOI: 10.1021/Jo00077A005 |
0.514 |
|
| 1993 |
Heerding DA, Hong CY, Kado N, Look GC, Overman LE. Simple method for controlling stereoselection in Mannich cyclization reactions of aldehydes The Journal of Organic Chemistry. 58: 6947-6948. DOI: 10.1021/Jo00077A004 |
0.438 |
|
| 1993 |
Montgomery J, Overman LE. Introduction of the 2-(phenylthio)ethyl, 2-(phenylsulfinyl)ethyl, and 2,2-bis(phenylthio)ethyl substituents into cyclic ketones The Journal of Organic Chemistry. 58: 6476-6479. DOI: 10.1021/Jo00075A054 |
0.618 |
|
| 1993 |
Kucera DJ, O'Connor SJ, Overman LE. Total synthesis of (.+-.)-scopadulcic acid A. An illustration of the utility of palladium catalyzed polyene cyclizations The Journal of Organic Chemistry. 58: 5304-5306. DOI: 10.1021/Jo00072A006 |
0.465 |
|
| 1993 |
Overman LE, Shim J. Synthesis applications of cationic aza-Cope rearrangements. Part 25. Total synthesis of Amaryllidaceae alkaloids of the 5,11-methanomorphanthridine type. Efficient total syntheses of (-)-pancracine and (.+-.)-pancracine The Journal of Organic Chemistry. 58: 4662-4672. DOI: 10.1021/Jo00069A032 |
0.524 |
|
| 1993 |
Overman LE, Rabinowitz MH. Studies toward the total synthesis of (+)-ptilomycalin A. Use of a tethered Biginelli condensation for the preparation of an advanced tricyclic intermediate The Journal of Organic Chemistry. 58: 3235-3237. DOI: 10.1021/Jo00064A007 |
0.493 |
|
| 1993 |
Grese TA, Hutchinson KD, Overman LE. General approach to halogenated tetrahydrofuran natural products from red algae of the genus Laurencia. Total synthesis of (±)-kumausallene and (±)-1-epi-kumausallene Journal of Organic Chemistry. 58: 2468-2477. DOI: 10.1021/Jo00061A021 |
0.402 |
|
| 1993 |
Hong CY, Kado N, Overman LE. Asymmetric synthesis of either enantiomer of opium alkaloids and morphinans. Total synthesis of (-)- and (+)-dihydrocodeinone and (-)- and (+)-morphine Journal of the American Chemical Society. 115: 11028-11029. DOI: 10.1021/Ja00076A086 |
0.455 |
|
| 1993 |
Berger D, Overman LE, Renhowe PA. Enantioselective total synthesis of (+)-isolaurepinnacin Journal of the American Chemical Society. 115: 9305-9306. DOI: 10.1021/Ja00073A063 |
0.516 |
|
| 1993 |
Knight SD, Overman LE, Pairaudeau G. Enantioselective total synthesis of (-)-strychnine Journal of the American Chemical Society. 115: 9293-9294. DOI: 10.1021/Ja00073A057 |
0.516 |
|
| 1993 |
Angle SR, Fevig JM, Knight SD, Marquis RW, Overman LE. Synthesis applications of cationic aza-Cope rearrangements. 24. The aza-Cope-Mannich approach to Strychnos alkaloids. Short stereocontrolled total syntheses of (.+-.)-dehydrotubifoline and (.+-.)-akuammicine Journal of the American Chemical Society. 115: 3966-3976. DOI: 10.1021/Ja00063A016 |
0.697 |
|
| 1993 |
Hirst GC, Johnson TO, Overman LE. First total synthesis of Lycopodium alkaloids of the magellanane group. Enantioselective total syntheses of (-)-magellanine and (+)-magellaninone Journal of the American Chemical Society. 115: 2992-2993. DOI: 10.1021/Ja00060A064 |
0.459 |
|
| 1993 |
Overman LE, Ricca DJ, Tran VD. First total synthesis of scopadulcic acid B Journal of the American Chemical Society. 115: 2042-2044. DOI: 10.1021/Ja00058A064 |
0.363 |
|
| 1993 |
Castro P, Overman LE, Zhang X, Mariano PS. Preparation of enantioenriched tetrahydropyridines by iminium ion-vinylsilane cyclizations Tetrahedron Letters. 34: 5243-5246. DOI: 10.1016/S0040-4039(00)73963-3 |
0.33 |
|
| 1992 |
Overman LE, Abelman MM, Kucera DJ, Tran VD, Ricca DJ. Palladium-catalyzed, polyene cyclizations Pure and Applied Chemistry. 64: 1813-1819. DOI: 10.1351/Pac199264121813 |
0.476 |
|
| 1992 |
Overman LE, Rodriguez-Campos IM. Preparation of Unsaturated Seven and Eight Membered Nitrogen Heterocycles by Iodide-Promoted Alkyne-Iminium Ion Cyclizations Synlett. 1992: 995-996. DOI: 10.1055/S-1992-21560 |
0.385 |
|
| 1992 |
Ashimori A, Overman LE. Catalytic asymmetric synthesis of quarternary carbon centers. Palladium-catalyzed formation of either enantiomer of spirooxindoles and related spirocyclics using a single enantiomer of a chiral diphosphine ligand The Journal of Organic Chemistry. 57: 4571-4572. DOI: 10.1021/Jo00043A005 |
0.491 |
|
| 1992 |
Goldstein SW, Overman LE, Rabinowitz MH. The first enantioselective total syntheses of the allopumiliotoxin A alkaloids 267A and 339B The Journal of Organic Chemistry. 57: 1179-1190. DOI: 10.1021/Jo00030A026 |
0.356 |
|
| 1992 |
Overman LE, Sharp MJ. Reaction of Na2Fe(CO)4 with an unsaturated aziridinium ion. Unprecedented rearrangement of an alkyltetracarbonylferrate intermediate The Journal of Organic Chemistry. 57: 1035-1038. DOI: 10.1021/Jo00029A054 |
0.339 |
|
| 1992 |
Overman LE, Robinson LA, Zablocki J. First total synthesis of (+)-allopumiliotoxin 339A. A practical entry to dendrobatid alkaloids of the allopumiliotoxin class Journal of the American Chemical Society. 114: 368-369. DOI: 10.1021/Ja00027A061 |
0.324 |
|
| 1992 |
Overman LE. Charge as a key component in reaction design. The invention of cationic cyclization reactions of importance in synthesis Accounts of Chemical Research. 25: 352-359. DOI: 10.1021/Ar00020A005 |
0.394 |
|
| 1992 |
Overman LE, Sarkar AK. Iodide-promoted aldiminium ion-alkyne cyclizations. A convenient synthesis of substituted tetrahydropyridines and 3-alkylidenepiperidines. Tetrahedron Letters. 33: 4103-4106. DOI: 10.1016/S0040-4039(00)74663-6 |
0.473 |
|
| 1992 |
Madin A, Overman LE. Controlling stereoselection in intramolecular heck reactions by tailoring the palladium catalyst Tetrahedron Letters. 33: 4859-4862. DOI: 10.1016/S0040-4039(00)61217-0 |
0.35 |
|
| 1991 |
Overman LE, Shim J. Synthesis applications of cationic aza-Cope rearrangements. 23. First total synthesis of amaryllidaceae alkaloids of the 5,11-methano morphanthridine type. An efficient total synthesis of (.+-.)-pancracine The Journal of Organic Chemistry. 56: 5005-5007. DOI: 10.1021/Jo00017A002 |
0.478 |
|
| 1991 |
Brown MJ, Overman LE. Preparation of 3-amino-4-(hydroxymethyl)azetidin-2-ones from the reaction of glycine enolates with imines of a glycoaldehyde The Journal of Organic Chemistry. 56: 1933-1936. DOI: 10.1021/Jo00005A048 |
0.444 |
|
| 1991 |
Brown MJ, Harrison T, Overman LE. General approach to halogenated tetrahydrofuran natural products from red algae of the genus Laurencia. Total synthesis of (.+-.)-trans-kumausyne and demonstration of an asymmetric synthesis strategy Journal of the American Chemical Society. 113: 5378-5384. DOI: 10.1021/Ja00014A032 |
0.461 |
|
| 1991 |
Brown MJ, Harrison T, Herrinton PM, Hopkins MH, Hutchinson KD, Overman LE, Mishra P. Acid-promoted reaction of cyclic allylic diols with carbonyl compounds. Stereoselective ring-enlarging tetrahydrofuran annulations Journal of the American Chemical Society. 113: 5365-5378. DOI: 10.1021/Ja00014A031 |
0.431 |
|
| 1991 |
Hopkins MH, Overman LE, Rishton GM. Stereocontrolled preparation of tetrahydrofurans from acid-promoted rearrangements of allylic acetals Journal of the American Chemical Society. 113: 5354-5365. DOI: 10.1021/Ja00014A030 |
0.515 |
|
| 1991 |
Fevig JM, Marquis RW, Overman LE. New approach to Strychnos alkaloids. Stereocontrolled total synthesis of (.+-.)-dehydrotubifoline Journal of the American Chemical Society. 113: 5085-5086. DOI: 10.1021/Ja00013A068 |
0.367 |
|
| 1991 |
Overman LE, Robertson GM, Robichaud AJ. Use of aza-Cope rearrangement-Mannich cyclization reactions to achieve a general entry to Melodinus and Aspidosperma alkaloids. Stereocontrolled total syntheses of (.+-.)-deoxoapodine, (.+-.)-meloscine, and (.+-.)-epimeloscine and a formal synthesis of (.+-.)-1-acetylaspidoalbidine Journal of the American Chemical Society. 113: 2598-2610. DOI: 10.1021/Ja00007A038 |
0.444 |
|
| 1991 |
Flann CJ, Overman LE, Sarkar AK. Synthesis of 3-acyl-3-alkyloxindoles Tetrahedron Letters. 32: 6993-6996. DOI: 10.1016/0040-4039(91)85022-W |
0.456 |
|
| 1991 |
Johnson TO, Overman LE. Ring-enlarging cyclopentene annulations Tetrahedron Letters. 32: 7361-7364. DOI: 10.1016/0040-4039(91)80107-H |
0.406 |
|
| 1990 |
Fisher MJ, Overman LE. Intramolecular N-(acyloxy)iminium ion-alkyne cycloadditions. A new route to bicyclic .alpha.-amino ketones The Journal of Organic Chemistry. 55: 1447-1459. DOI: 10.1021/Jo00292A014 |
0.441 |
|
| 1990 |
Abelman MM, Overman LE, Tran VD. Construction of quaternary carbon centers by palladium-catalyzed intramolecular alkene insertions. Total synthesis of the Amaryllidaceae alkaloids (.+-.)-tazettine and (.+-.)-6a-epipretazettine Journal of the American Chemical Society. 112: 6959-6964. DOI: 10.1021/Ja00175A033 |
0.454 |
|
| 1990 |
Blumenkopf TA, Look GC, Overman LE. Formation of .DELTA.4-oxocenes from Lewis acid promoted cyclizations of 5-hexenyl acetals. Evidence for a concerted ene cyclization mechanism Journal of the American Chemical Society. 112: 4399-4403. DOI: 10.1021/Ja00167A042 |
0.35 |
|
| 1990 |
Blumenkopf TA, Bratz M, Castaneda A, Look GC, Overman LE, Rodriguez D, Thompson AS. Preparation of eight-membered cyclic ethers by Lewis acid promoted acetal-alkene cyclizations Journal of the American Chemical Society. 112: 4386-4399. DOI: 10.1021/Ja00167A041 |
0.405 |
|
| 1990 |
Overman LE, Renaldo AE. Catalyzed sigmatropic rearrangements. 10. Mechanism of the palladium dichloride catalyzed Cope rearrangement of acyclic dienes. A substituent effect study Journal of the American Chemical Society. 112: 3945-3949. DOI: 10.1021/Ja00166A034 |
0.447 |
|
| 1990 |
ABELMAN MM, OVERMAN LE, TRAN VD. ChemInform Abstract: Construction of Quaternary Carbon Centers by Palladium-Catalyzed Intramolecular Alkene Insertions. Total Synthesis of the Amaryllidaceae Alkaloids (.+-.)-Tazettine and (.+-.)-6a-Epipretazettine. Cheminform. 21. DOI: 10.1002/chin.199052339 |
0.368 |
|
| 1990 |
BLUMENKOPF TA, BRATZ M, CASTANEDA A, LOOK GC, OVERMAN LE, RODRIGUEZ D, THOMPSON AS. ChemInform Abstract: Preparation of Eight-Membered Cyclic Ethers by Lewis Acid Promoted Acetal-Alkene Cyclizations. Cheminform. 21. DOI: 10.1002/chin.199037232 |
0.303 |
|
| 1990 |
OVERMAN LE, RENALDO AF. ChemInform Abstract: Catalyzed Sigmatropic Rearrangements. Part 10. Mechanism of the Palladium Dichloride Catalyzed Cope Rearrangement of Acyclic Dienes. A Substituent Effect Study. Cheminform. 21. DOI: 10.1002/chin.199035079 |
0.353 |
|
| 1990 |
CARPENTER NE, KUCERA DJ, OVERMAN LE. ChemInform Abstract: Palladium-Catalyzed Polyene Cyclizations of Trienyl Triflates. Cheminform. 21. DOI: 10.1002/chin.199024074 |
0.405 |
|
| 1990 |
CASTANEDA A, KUCERA DJ, OVERMAN LE. ChemInform Abstract: Preparation of Seven-Membered Ring Cyclic Ethers and 3-Alkylidenetetrahydropyrans from the Cyclization of Oxonium Cations Derived from Unsubstituted and Silicon-Containing 4-Alken-1-ols. Cheminform. 21. DOI: 10.1002/chin.199019090 |
0.333 |
|
| 1989 |
Carpenter NE, Kucera DJ, Overman LE. Palladium-catalyzed polyene cyclizations of trienyl triflates Journal of Organic Chemistry. 54: 5846-5848. DOI: 10.1021/Jo00286A009 |
0.327 |
|
| 1989 |
Castaneda A, Kucera DJ, Overman LE. Preparation of seven-membered ring cyclic ethers and 3-alkylidenetetrahydropyrans from the cyclization of oxonium cations derived from unsubstituted and silicon-containing 4-alken-1-ols Journal of Organic Chemistry. 54: 5695-5707. DOI: 10.1021/Jo00285A016 |
0.385 |
|
| 1989 |
Heitz MP, Overman LE. Complementary use of iminium ion and N-acyl iminium ion cyclization initiators for asymmetric synthesis of both enantiomers of hydroxylated indolizidines The Journal of Organic Chemistry. 54: 2591-2596. DOI: 10.1021/Jo00272A025 |
0.341 |
|
| 1989 |
Overman LE, Robertson GM, Robichaud AJ. Synthesis applications of cationic aza-Cope rearrangements. 20. Total synthesis of (.+-.)-meloscine and (.+-.)-epimeloscine Journal of Organic Chemistry. 54: 1236-1238. DOI: 10.1021/Jo00267A003 |
0.486 |
|
| 1989 |
Hirst GC, Howard PN, Overman LE. Stereocontrolled construction of carbocyclic rings by sequential cationic cyclization-pinacol rearrangements Journal of the American Chemical Society. 111: 1514-1515. DOI: 10.1021/Ja00186A065 |
0.391 |
|
| 1989 |
Overman LE, Robichaud AJ. Total syntheses of (+)-geissoschizine, (.+-.)-geissoschizine, and (.+-.)-(Z)-isositsirikine. Stereocontrolled synthesis of exocyclic double bonds by stereospecific iminium ion-vinylsilane cyclizations Journal of the American Chemical Society. 111: 300-308. DOI: 10.1021/Ja00183A046 |
0.399 |
|
| 1989 |
Overman LE, Wild H. Preparation of functionalized hydroindol-3-ols via tandem aza-Cope rearrangement-mannich cyclizations. Formal total synthesis of (±)-6a-epipretazettine and related alkaloids Tetrahedron Letters. 30: 647-650. DOI: 10.1016/S0040-4039(01)80272-0 |
0.41 |
|
| 1989 |
OVERMAN LE, WILD H. ChemInform Abstract: Preparation of Functionalized Hydroindol-3-ols via Tandem Aza-Cope Rearrangement-Mannich Cyclizations. Formal Total Synthesis of (.+-.)-6a-Epipretazettine and Related Alkaloids. Cheminform. 20. DOI: 10.1002/chin.198932303 |
0.32 |
|
| 1989 |
EARLEY WG, JACOBSEN EJ, MEIER GP, OH T, OVERMAN LE. ChemInform Abstract: Synthesis Studies Directed Toward Gelsemine. A New Synthesis of Highly Functionalized cis-Hydroisoquinolines. Cheminform. 20. DOI: 10.1002/chin.198902187 |
0.331 |
|
| 1988 |
Daly JW, McNeal E, Gusovsky F, Ito F, Overman LE. Pumiliotoxin alkaloids: relationship of cardiotonic activity to sodium channel activity and phosphatidylinositol turnover. Journal of Medicinal Chemistry. 31: 477-80. PMID 2448459 DOI: 10.1021/Jm00397A036 |
0.301 |
|
| 1988 |
Fisher MJ, Overman LE. Synthesis and Diels-Alder reactions of 5-alkenyl-1,3-oxathiole 3-oxides. A new class of diheterosubstituted 1,3-dienes The Journal of Organic Chemistry. 53: 2630-2634. DOI: 10.1021/Jo00246A047 |
0.381 |
|
| 1988 |
Doedens RJ, Meier GP, Overman LE. Synthesis applications of cationic aza-Cope rearrangements. Part 17. Transition-state geometry of [3,3]-sigmatropic rearrangements of iminium ions Journal of Organic Chemistry. 53: 685-690. DOI: 10.1021/Jo00238A039 |
0.329 |
|
| 1988 |
Overman LE, Sharp MJ. Nucleophile-promoted electrophilic cyclization reactions of alkynes [Erratum to document cited in CA108(7):55853J] Journal of the American Chemical Society. 110: 5934-5934. DOI: 10.1021/Ja00225A074 |
0.339 |
|
| 1988 |
Fisher MJ, Hehre WJ, Kahn SD, Overman LE. Face selectivity in Diels-Alder reactions of chiral dienes containing allylic substituents Journal of the American Chemical Society. 110: 4625-4633. DOI: 10.1021/Ja00222A022 |
0.376 |
|
| 1988 |
Jacobsen EJ, Levin J, Overman LE. Synthesis applications of cationic aza-Cope rearrangements. Part 18. Scope and mechanism of tandem cationic aza-Cope rearrangement-Mannich cyclization reactions Journal of the American Chemical Society. 110: 4329-4336. DOI: 10.1021/Ja00221A037 |
0.395 |
|
| 1988 |
Abelman MM, Overman LE. Palladium-catalyzed polyene cyclizations of dienyl aryl iodides Journal of the American Chemical Society. 110: 2328-2329. DOI: 10.1021/Ja00215A068 |
0.5 |
|
| 1988 |
Overman LE, Thompson AS. Total synthesis of (-)-laurenyne. Use of acetal-initiated cyclizations to prepare functionalized eight-membered cyclic ethers Journal of the American Chemical Society. 110: 2248-2256. DOI: 10.1021/Ja00215A040 |
0.484 |
|
| 1988 |
Overman LE, Sharp MJ. Nucleophile-promoted electrophilic cyclization reactions of alkynes Journal of the American Chemical Society. 110: 612-614. DOI: 10.1021/Ja00210A058 |
0.412 |
|
| 1988 |
Overman LE, Sharp MJ. Enantioselective total synthesis of the pumiliotoxin a alkaloids via reductive iminium ion-alkyne cyclizations. Total synthesis of (+)-pumiliotoxin a Tetrahedron Letters. 29: 901-904. DOI: 10.1016/S0040-4039(00)82477-6 |
0.537 |
|
| 1988 |
Lett RM, Overman LE, Zablocki J. Synthesis of allopumiliotoxin A alkaloids via iminium ion-vinylsilane cyclizations Tetrahedron Letters. 29: 6541-6544. DOI: 10.1016/S0040-4039(00)82392-8 |
0.456 |
|
| 1988 |
Earley WG, Oh T, Overman LE. Synthesis studies directed toward gelsemine. Preparation of an advanced pentacyclic intermediate Tetrahedron Letters. 29: 3785-3788. DOI: 10.1016/S0040-4039(00)82114-0 |
0.513 |
|
| 1988 |
Daub GW, Heerding DA, Overman LE. Synthesis of substituted tetrahydropyridines by cyclizations of silicon-containing iminium ions Tetrahedron. 44: 3919-3930. DOI: 10.1016/S0040-4020(01)86645-X |
0.376 |
|
| 1988 |
FISHER MJ, HEHRE WJ, KAHN SD, OVERMAN LE. ChemInform Abstract: Face Selectivity in Diels-Alder Reactions of Chiral Dienes Containing Allylic Substituents. Cheminform. 19. DOI: 10.1002/chin.198845084 |
0.31 |
|
| 1988 |
FISHER MJ, OVERMAN LE. ChemInform Abstract: Synthesis and Diels-Alder Reactions of 5-Alkenyl-1,3-oxathiole 3-Oxides. A New Class of Diheterosubstituted 1,3-Dienes. Cheminform. 19. DOI: 10.1002/chin.198843198 |
0.303 |
|
| 1988 |
OVERMAN LE, THOMPSON AS. ChemInform Abstract: Total Synthesis of (-)-Laurenyne. Use of Acetal-Initiated Cyclizations to Prepare Functionalized Eight-Membered Cyclic Ethers. Cheminform. 19. DOI: 10.1002/chin.198829292 |
0.391 |
|
| 1988 |
ABELMAN MM, OVERMAN LE. ChemInform Abstract: Palladium-Catalyzed Polyene Cyclizations of Dienyl Aryl Iodides. Cheminform. 19. DOI: 10.1002/chin.198829144 |
0.405 |
|
| 1988 |
OVERMAN LE, SHARP MJ. ChemInform Abstract: Nucleophile-Promoted Electrophilic Cyclization Reactions of Alkynes. Cheminform. 19. DOI: 10.1002/chin.198818208 |
0.317 |
|
| 1988 |
FLANN CJ, OVERMAN LE. ChemInform Abstract: Enantioselective Total Synthesis of Streptazolin. The Tandem Use of Iminium Ion-Vinylsilane Cyclizations and Intramolecular Acylations. Cheminform. 19. DOI: 10.1002/chin.198803348 |
0.332 |
|
| 1987 |
Abelman MM, Oh T, Overman LE. Intramolecular alkene arylations for rapid assembly of polycyclic systems containing quaternary centers. A new synthesis of spirooxindoles and other fused and bridged ring systems The Journal of Organic Chemistry. 52: 4130-4133. DOI: 10.1021/Jo00227A038 |
0.37 |
|
| 1987 |
Flann CJ, Overman LE. Enantioselective total synthesis of streptazolin. The tandem use of iminium ion vinylsilane cyclizations and intramolecular acylations Journal of the American Chemical Society. 109: 6115-6118. DOI: 10.1021/Ja00254A034 |
0.322 |
|
| 1987 |
McCann SF, Overman LE. Medium effects and the nature of the rate-determining step in Mannich-type cyclizations Journal of the American Chemical Society. 109: 6107-6114. DOI: 10.1021/Ja00254A033 |
0.312 |
|
| 1987 |
Flann C, Malone TC, Overman LE. Iminium ion and acyliminium ion initiated cyclization reactions of vinylsilanes. Regiocontrolled synthesis of tetrahydropyridines and related heterocycles Journal of the American Chemical Society. 109: 6097-6107. DOI: 10.1021/Ja00254A032 |
0.356 |
|
| 1987 |
Hopkins MH, Overman LE. Stereocontrolled preparation of tetrahydrofurans by acid-catalyzed rearrangement of allylic acetals Journal of the American Chemical Society. 109: 4748-4749. DOI: 10.1021/Ja00249A063 |
0.41 |
|
| 1987 |
HOPKINS MH, OVERMAN LE. ChemInform Abstract: Stereocontrolled Preparation of Tetrahydrofurans by Acid-Catalyzed Rearrangement of Allylic Acetals. Cheminform. 18. DOI: 10.1002/chin.198747183 |
0.311 |
|
| 1986 |
Overman LE, Castaneda A, Blumenkopf TA. Acetal-initiated cyclizations of vinylsilanes. A general synthesis of allylically unsaturated oxacyclics Journal of the American Chemical Society. 108: 1303-1304. DOI: 10.1021/Ja00266A034 |
0.34 |
|
| 1986 |
Blumenkopf TA, Overman LE. Vinylsilane- and alkynylsilane-terminated cyclization reactions Chemical Reviews. 86: 857-873. DOI: 10.1021/Cr00075A009 |
0.375 |
|
| 1986 |
Overman LE, Okazaki ME, Mishra P. -Butyldiphenylsilylamines: A useful protecting group for primary amines Tetrahedron Letters. 27: 4391-4394. DOI: 10.1016/S0040-4039(00)84960-6 |
0.37 |
|
| 1986 |
Overman LE, Blumenkopf TA, Castaneda A, Thompson AS. Efficient preparations of 8- and 9-membered cyclic ethers Journal of the American Chemical Society. 108: 3516-3517. DOI: 10.1002/Chin.198642226 |
0.401 |
|
| 1986 |
OVERMAN LE, BLUMENKOPF TA, CASTANEDA A, THOMPSON AS. ChemInform Abstract: Efficient Preparations of 8- and 9-Membered Cyclic Ethers. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198642226 |
0.307 |
|
| 1986 |
OVERMAN LE, LIN N. ChemInform Abstract: Enantioselective Total Synthesis of (+)-Pumiliotoxin A. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198616340 |
0.521 |
|
| 1986 |
OVERMAN LE, ANGLE SR. ChemInform Abstract: Synthesis Applications of Cationic Aza-Cope Rearrangements. Stereocontrolled Synthesis of Hexahydro-1H-pyrrolo[2,3-d]carbazoles. Chemischer Informationsdienst. 17. DOI: 10.1002/chin.198610366 |
0.665 |
|
| 1986 |
OVERMAN LE, LESUISSE D. ChemInform Abstract: The Synthesis of Indolizidines by Intramolecular Ene Cyclizations. Chemischer Informationsdienst. 17. DOI: 10.1002/Chin.198604184 |
0.537 |
|
| 1985 |
Daly JW, McNeal ET, Overman LE, Ellison DH. A new class of cardiotonic agents: structure-activity correlations for natural and synthetic analogues of the alkaloid A new class of A new class of cardiotonic agents: structure-activity correlations for natural and synthetic analogues of the alkaloid pumiliotoxin B (8-hydroxy-8-methyl-6-alkylidene-1-azabicyclo[4.3.0]nonanes). Journal of Medicinal Chemistry. 28: 482-6. PMID 3981541 DOI: 10.1021/Jm00382A017 |
0.304 |
|
| 1985 |
Overman LE, Lin NH. Enantioselective total synthesis of (+)-pumiliotoxin A Journal of Organic Chemistry. 50: 3669-3670. DOI: 10.1021/Jo00219A060 |
0.435 |
|
| 1985 |
Overman LE, Okazaki ME, Jacobsen EJ. Synthesis applications of cationic aza-Cope rearrangements. 16. Stereocontrolled synthesis of substituted cis-cyclopenta[b]pyrrolidines The Journal of Organic Chemistry. 50: 2403-2405. DOI: 10.1021/Jo00213A049 |
0.481 |
|
| 1985 |
Overman LE, Lesuisse D. The synthesis of indolizidines by intramolecular ene cyclizations. Preparation of (E)-alkylidene analogs of pumiliotoxin A. Tetrahedron Letters. 26: 4167-4170. DOI: 10.1016/S0040-4039(00)98981-0 |
0.511 |
|
| 1985 |
Overman LE, Sugai S. Total Synthesis of (?)-Crinine. Use of Tandem Cationic Aza-Cope Rearrangement/Mannich Cyclizations for the Synthesis of Enantiomerically PureAmaryllidaceae Alkaloids Helvetica Chimica Acta. 68: 745-749. DOI: 10.1002/Hlca.19850680324 |
0.518 |
|
| 1985 |
Overman LE. Heterocyclization Reactions Employing Vinylsilane Terminators Cheminform. 17: 59-67. DOI: 10.1002/Chin.198619360 |
0.365 |
|
| 1985 |
Overman LE, Angle SR. Synthesis applications of cationic aza-Cope rearrangements. Stereocontrolled synthesis of hexahydro-1H-pyrrolo[2,3-d]carbazoles The Journal of Organic Chemistry. 50: 4021-4028. DOI: 10.1002/Chin.198610366 |
0.686 |
|
| 1985 |
OVERMAN LE, SUGAI S. ChemInform Abstract: SYNTHESIS APPLICATIONS OF AZA-COPE REARRANGEMENTS. PART 14. TOTAL SYNTHESIS OF (-)-CRININE. USE OF TANDEM CATIONIC AZA-COPE REARRANGEMENT/MANNICH CYCLIZATIONS FOR THE SYNTHESIS OF ENANTIOMERICALLY PURE AMARYLLIDACEAE ALKALOIDS Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198535320 |
0.431 |
|
| 1985 |
DALY JW, MCNEAL ET, OVERMAN LE, ELLISON DH. ChemInform Abstract: A NEW CLASS OF CARDIOTONIC AGENTS: STRUCTURE-ACTIVITY CORRELATIONS FOR NATURAL AND SYNTHETIC ANALOGS OF THE ALKALOID PUMILIOTOXIN (8-HYDROXY-8-METHYL-6-ALKYLIDENE-1-AZABICYCLO(4.3.0)NONANES) Chemischer Informationsdienst. 16. DOI: 10.1002/Chin.198531232 |
0.309 |
|
| 1985 |
OVERMAN LE, BURK RM. ChemInform Abstract: A CONVENIENT SYNTHESIS OF Δ1-PYRROLINES AND Δ1-PIPERIDINES Chemischer Informationsdienst. 16. DOI: 10.1002/chin.198519196 |
0.381 |
|
| 1984 |
Overman LE, Goldstein SW. Enantioselective total synthesis of allopumiliotoxin A alkaloids 267A and 339B Journal of the American Chemical Society. 106: 5360-5361. DOI: 10.1021/Ja00330A059 |
0.367 |
|
| 1984 |
Overman LE, Bell KL, Ito F. Enantioselective total syntheses of pumiliotoxin B and pumiliotoxin 251D. A general entry to the pumiliotoxin A alkaloids via stereospecific iminium ion-vinylsilane cyclizations Journal of the American Chemical Society. 106: 4192-4201. DOI: 10.1021/Ja00327A022 |
0.334 |
|
| 1984 |
Overman LE, Burk RM. The importance of vinylsilane stereochemistry and σ - π stabilization in iminium ion-vinylsilane cyclizations. A short total synthesis of the alkaloid (−) −epielwesine. Tetrahedron Letters. 25: 5739-5742. DOI: 10.1016/S0040-4039(01)81674-9 |
0.403 |
|
| 1984 |
Overman LE, Burk RM. A convenient synthesis of Δ1-pyrrolines and Δ1- piperideines Tetrahedron Letters. 25: 5737-5738. DOI: 10.1016/S0040-4039(01)81673-7 |
0.51 |
|
| 1984 |
Overman LE, Burk RM. A convenient synthesis of unsymmetrical secondary amines. formation of unstable formaldehyde imines. Tetrahedron Letters. 25: 1635-1638. DOI: 10.1016/S0040-4039(01)81131-X |
0.449 |
|
| 1984 |
OVERMAN LE, BURK RM. ChemInform Abstract: A CONVENIENT SYNTHESIS OF UNSYMMETRICAL SECONDARY AMINES. IN SITU FORMATION OF UNSTABLE FORMALDEHYDE IMINES Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198433143 |
0.409 |
|
| 1984 |
OVERMAN LE, KAKIMOTO M, OKAZAKI ME, MEIER GP. ChemInform Abstract: SYNTHESIS APPLICATIONS OF AZA-COPE REARRANGEMENTS. 11. CARBON-CARBON BOND FORMATION UNDER MILD CONDITIONS VIA TANDEM CATIONIC AZA-COPE REARRANGEMENT-MANNICH REACTIONS. A CONVENIENT SYNTHESIS OF POLYSUBSTITUTED PYRROLIDINES Chemischer Informationsdienst. 15. DOI: 10.1002/chin.198406168 |
0.377 |
|
| 1984 |
Overman LE. Mercury(II)- and Palladium(II)-Catalyzed [3,3]-Sigmatropic Rearrangements [New Synthetic Methods (46)] Angewandte Chemie International Edition in English. 23: 579-586. DOI: 10.1002/Anie.198405791 |
0.37 |
|
| 1983 |
Overman LE, Jacobsen EJ, Doedens RJ. Synthesis applications of cationic aza-Cope rearrangements. Part 13. Stereoselective synthesis of cis- and trans-3a-aryl-4-oxodecahydrocyclohepta[b]pyrroles The Journal of Organic Chemistry. 48: 3393-3400. DOI: 10.1021/Jo00168A006 |
0.434 |
|
| 1983 |
Overman LE, Sworin M, Burk RM. Synthesis applications of aza-Cope rearrangements. Part 10. A new approach for the total synthesis of pentacyclic Aspidosperma alkaloids. Total synthesis of dl-16-methoxytabersonine The Journal of Organic Chemistry. 48: 2685-2690. DOI: 10.1021/Jo00164A011 |
0.472 |
|
| 1983 |
Overman LE, Mendelson LT, Jacobsen EJ. Synthesis applications of aza-Cope rearrangements. 12. Applications of cationic aza-Cope rearrangements for alkaloid synthesis. Stereoselective preparation of cis-3a-aryloctahydroindoles and a new short route to Amaryllidaceae alkaloids Journal of the American Chemical Society. 105: 6629-6637. DOI: 10.1021/Ja00360A014 |
0.411 |
|
| 1983 |
Overman LE, Kakimoto M, Okazaki ME, Meier GP. Synthesis applications of aza-Cope rearrangements. 11. Carbon-carbon bond formation under mild conditions via tandem cationic aza-Cope rearrangement-Mannich reactions. A convenient synthesis of polysubstituted pyrrolidines Journal of the American Chemical Society. 105: 6622-6629. DOI: 10.1021/Ja00360A013 |
0.464 |
|
| 1983 |
Overman LE, Lesuisse D, Hashimoto M. Synthetic applications of N-acylamino-1,3-dienes. 10. Importance of allylic interactions and stereoelectronic effects in dictating the steric course of the reaction of iminium ions with nucleophiles. An efficient total synthesis of (.+-.)-gephyrotoxin Journal of the American Chemical Society. 105: 5373-5379. DOI: 10.1021/Ja00354A031 |
0.433 |
|
| 1983 |
Overman LE, Renaldo AF. Palladium dichloride catalyzed cope rearrangements of functionalized acyclic 1,5-dienes Tetrahedron Letters. 24: 3757-3760. DOI: 10.1016/S0040-4039(00)94527-1 |
0.471 |
|
| 1983 |
Overman LE, Renaldo AF. Palladium dichloride-promoted cyclizations of 1,5-dienes. A new method for forming cyclohexenes. Tetrahedron Letters. 24: 2235-2238. DOI: 10.1016/S0040-4039(00)81892-4 |
0.417 |
|
| 1983 |
Overman LE, Petty CB, Ban T, Huang GT. Preparation and Diels-Alder reactions of 1,3-dienes containing both sulfur and nitrogen substituents. Complete orientational control by the acylamino group Journal of the American Chemical Society. 105: 6335-6337. DOI: 10.1002/Chin.198402092 |
0.402 |
|
| 1983 |
OVERMAN LE, RENALDO AF. ChemInform Abstract: CATALYZED SIGMATROPIC REARRANGEMENTS. 8. PALLADIUM DICHLORIDE-CATALYZED COPE REARRANGEMENTS OF FUNCTIONALIZED ACYCLIC 1,5-DIENES Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198351102 |
0.35 |
|
| 1983 |
OVERMAN LE, LESUISSE D, HASHIMOTO M. ChemInform Abstract: SYNTHETIC APPLICATIONS OF N-ACYLAMINO-1,3-DIENES. 10. IMPORTANCE OF ALLYLIC INTERACTIONS AND STEREOELECTRONIC EFFECTS IN DICTATING THE STERIC COURSE OF THE REACTION OF IMINIUM IONS WITH NUCLEOPHILES. AN EFFICIENT TOTAL SYNTHESIS OF (. Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198347324 |
0.335 |
|
| 1983 |
OVERMAN LE, RENALDO AF. ChemInform Abstract: CATALYZED SIGMATROPIC REARRANGEMENTS. 7. PALLADIUM DICHLORIDE-PROMOTED CYCLIZATIONS OF 1,5-DIENES. A NEW METHOD FOR FORMING CYCLOHEXENES Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198339178 |
0.323 |
|
| 1983 |
OVERMAN LE, MALONE TC. ChemInform Abstract: STEREOCONTROLLED SYNTHESIS OF EXOCYCLIC TRISUBSTITUTED DOUBLE BONDS BY STEREOSPECIFIC IMINIUM ION-VINYLSILANE CYCLIZATIONS. A SHORT SYNTHETIC ROUTE TO INDOLOQUINOLIZIDINE ALKALOIDS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198321233 |
0.304 |
|
| 1983 |
OVERMAN LE, MCCREADY RJ. ChemInform Abstract: CARBONYL PARTICIPATION IN THE REACTION OF N-ACYL-2-ISOPROPENYLPYRROLIDINES WITH HALOGEN ELECTROPHILES. STEREOCONTROLLED PREPARATION OF ENANTIOMERICALLY PURE SYNTHONS FOR THE SYNTHESIS OF PUMILIOTOXIN A ALKALOIDS Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198312207 |
0.394 |
|
| 1983 |
OVERMAN LE, JACOBSEN EJ. ChemInform Abstract: CATALYZED SIGMATROPIC REARRANGEMENTS. 6. CHAIR TOPOLOGY OF THE PALLADIUM DICHLORIDE CATALYZED COPE REARRANGEMENT OF ACYCLIC 1,5-DIENES Chemischer Informationsdienst. 14. DOI: 10.1002/chin.198312114 |
0.396 |
|
| 1982 |
Overman LE, Malone TC. Stereocontrolled synthesis of exocyclic trisubstituted double bonds by stereospecific iminium ion-vinylsilane cyclizations. A short synthetic route to indoloquinolizidine alkaloids The Journal of Organic Chemistry. 47: 5297-5300. DOI: 10.1021/Jo00148A013 |
0.406 |
|
| 1982 |
Overman LE, Jacobsen EJ. Chair topology of the palladium dichloride catalyzed Cope rearrangement of acyclic 1,5-dienes Journal of the American Chemical Society. 104: 7225-7231. DOI: 10.1021/Ja00389A054 |
0.472 |
|
| 1982 |
Overman LE, Jacobsen E. The cyanomethyl group for nitrogen protection and iminium ion generation in ring-enlarging pyrrolidine annulations. A short synthesis of the amaryllidaceae alkaloid d,1-crinine Tetrahedron Letters. 23: 2741-2744. DOI: 10.1016/S0040-4039(00)87446-8 |
0.376 |
|
| 1982 |
Overman LE, Jacobsen E. Synthesis applications of aza-cope rearrangements. Tetrahedron Letters. 23: 2737-2740. DOI: 10.1016/S0040-4039(00)87445-6 |
0.445 |
|
| 1982 |
Overman LE, Mendelson LT, Flippin LA. Synthesis applications of aza-cope rearrangements. Stereoselective synthesis of trans-alkyl-cis-3a-aryloctahydroindolones. Tetrahedron Letters. 23: 2733-2736. DOI: 10.1016/S0040-4039(00)87444-4 |
0.414 |
|
| 1982 |
Overman LE, McCready RJ. Highly stereocontrolled reduction of α′-alkoxyenones to give either the threo or eryhtro allylic 1,2-diol. Assignment of the threo configuration to the C-15, C-16 diol of pumiliotoxin B.1 Tetrahedron Letters. 23: 2355-2358. DOI: 10.1016/S0040-4039(00)87340-2 |
0.374 |
|
| 1982 |
Overman LE, McCready RJ. Carbonyl participation in the reaction of N-acyl-2-isopropenylpyrrolidines with halogen electrophiles. Stereocontrolled preparation of enantiomerically pure synthons for the synthesis of pumiliotoxin A alkaloids. Tetrahedron Letters. 23: 4887-4890. DOI: 10.1016/S0040-4039(00)85739-1 |
0.491 |
|
| 1982 |
OVERMAN L, MENDELSON LT, FLIPPIN LA. ChemInform Abstract: SYNTHESIS APPLICATIONS OF AZA-COPE REARRANGEMENTS. PART 7. STEREOSELECTIVE SYNTHESIS OF TRANS-2-ALKYL-CIS-3A-ARYLOCTAHYDROINDOLONES Chemischer Informationsdienst. 13. DOI: 10.1002/chin.198249209 |
0.331 |
|
| 1981 |
Overman LE, Freerks RL. A short total synthesis of (.+-.)-perhydrogephyrotoxin The Journal of Organic Chemistry. 46: 2833-2835. DOI: 10.1021/Jo00326A060 |
0.449 |
|
| 1981 |
Overman LE, Roos JP. Preparation of substituted 2-pyridones by thermal rearrangement of propargylic pseudoureas. Improvements in the 2-pyridone yields by variations of the pseudourea NR2 substituent The Journal of Organic Chemistry. 46: 811-813. DOI: 10.1021/Jo00317A035 |
0.354 |
|
| 1981 |
Overman LE, Mendelson LT. Synthesis applications of aza-Cope rearrangements. Stereoselective synthesis of cis-3a-aryloctahydroindoles and a new short entry to Amaryllidaceae alkaloids Journal of the American Chemical Society. 103: 5579-5581. DOI: 10.1021/Ja00408A055 |
0.422 |
|
| 1981 |
Overman LE, Freerks RL, Petty CB, Clizbe LA, Ono RK, Taylor GF, Jessup PJ. Diels-Alder reactions of 1-(acylamino)-1,3-dienes Journal of the American Chemical Society. 103: 2816-2822. DOI: 10.1021/Ja00400A054 |
0.361 |
|
| 1981 |
Overman LE, Clizbe LA, Freerks RL, Marlowe CK. Thermal rearrangements of propargylic trichloroacetimidates. Synthesis of (trichloroacetamido)-1,3-dienes and -1,2-dienes Journal of the American Chemical Society. 103: 2807-2815. DOI: 10.1021/Ja00400A053 |
0.403 |
|
| 1981 |
Overman LE, Bell KL. Enantiospecific total synthesis of dendrobatid toxin 251D. A short chiral entry to the cardiac-active pumiliotoxin A alkaloids via stereospecific iminium ion-vinylsilane cyclizations Journal of the American Chemical Society. 103: 1851-1853. DOI: 10.1021/Ja00397A052 |
0.369 |
|
| 1981 |
Overman LE, Sworin M, Bass LS, Clardy J. Synthesis applications of aza-cope rearrangements Tetrahedron. 37: 4041-4045. DOI: 10.1016/S0040-4020(01)93279-X |
0.499 |
|
| 1981 |
Overman LE, Flippin LA. Facile aminolysis of epoxides with diethylaluminum amides Tetrahedron Letters. 22: 195-198. DOI: 10.1016/0040-4039(81)80053-6 |
0.339 |
|
| 1981 |
OVERMAN LE, CLIZBE LA, FREERKS RL, MARLOWE CK. ChemInform Abstract: THERMAL REARRANGEMENTS OF PROPARGYLIC TRICHLOROACETIMIDATES. SYNTHESIS OF (TRICHLOROACETAMIDO)-1,3-DIENES AND -1,2-DIENES Chemischer Informationsdienst. 12. DOI: 10.1002/chin.198135135 |
0.303 |
|
| 1980 |
Overman LE, Yokomatsu T. Synthesis applications of directed 2-azonia-[3,3]-sigmatropic rearrangements. 4. A new method for stereoselective piperidine annulation. Directing the 2-azonia-[3,3]-sigmatropic rearrangement by irreversible hydrolysis The Journal of Organic Chemistry. 45: 5229-5230. DOI: 10.1021/jo01313a051 |
0.318 |
|
| 1980 |
Overman LE, Fukaya C. Stereoselective total synthesis of (.+-.)-perhydrogephyrotoxin. Synthetic applications of directed 2-azonia-[3,3]-sigmatropic rearrangements Journal of the American Chemical Society. 102: 1454-1456. DOI: 10.1021/Ja00524A057 |
0.478 |
|
| 1980 |
Overman LE, Knoll FM. Catalyzed sigmatropic rearrangements. 5. Palladium(II) chloride catalyzed Cope rearrangements of acyclic 1,5-dienes Journal of the American Chemical Society. 102: 865-867. DOI: 10.1021/Ja00522A082 |
0.402 |
|
| 1980 |
Overman LE, Tsuboi S, Roos JP, Taylor GF. Preparation of substituted 2-pyridones by thermal rearrangement of propargylic pyrrolidine pseudoureas Journal of the American Chemical Society. 102: 747-754. DOI: 10.1021/Ja00522A052 |
0.33 |
|
| 1980 |
Overman LE. Allylic and propargylic imidic esters in organic synthesis Accounts of Chemical Research. 13: 218-224. DOI: 10.1021/Ar50151A005 |
0.436 |
|
| 1980 |
OVERMAN LE. ChemInform Abstract: ALLYLIC AND PROPARGYLIC IMIDIC ESTERS IN ORGANIC SYNTHESIS Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198047336 |
0.336 |
|
| 1980 |
OVERMAN LE, KAKIMOTO M, OKAWARA M. ChemInform Abstract: DIRECTED 2-AZONIA-(3,3)-SIGMATROPIC REARRANGEMENTS. A CONVENIENT PREPARATION OF SUBSTITUTED 1-AZASPIRO(4,5)DECANES Chemischer Informationsdienst. 11. DOI: 10.1002/chin.198004228 |
0.333 |
|
| 1979 |
Overman LE, Petty CB, Doedens RJ. Synthetic applications of N-(acylamino)-1,3-dienes. Control of endo stereoselectivity by the acyl substituent. Stereospecific synthesis of the analgesic Tilidine Journal of Organic Chemistry. 11: 4183-4185. DOI: 10.1021/Jo01337A036 |
0.439 |
|
| 1979 |
Overman LE, Tsuboi S, Angle S. 4-Methylene-4,5-dihydrooxazoles: isolation, properties, and use for the preparation of substituted oxazoles The Journal of Organic Chemistry. 44: 2323-2325. DOI: 10.1021/Jo01327A076 |
0.64 |
|
| 1979 |
Overman LE, Kakimoto M. Carbon-carbon bond formation via directed 2-azonia-[3,3]-sigmatropic rearrangements. A new pyrrolidine synthesis Journal of the American Chemical Society. 101: 1310-1312. DOI: 10.1021/Ja00499A058 |
0.377 |
|
| 1979 |
Overman LE, Kakimoto M, Okawara M. Directed 2-azonia-[3,3]-sigmatropic rearrangements. a convenient preparation of substituted 1-azaspiro[4,5]decanes Tetrahedron Letters. 20: 4041-4044. DOI: 10.1016/S0040-4039(01)86498-4 |
0.441 |
|
| 1979 |
Overman LE, Knoll FM. Palladium (II) - catalyzed rearrangement of allylic acetates Tetrahedron Letters. 20: 321-324. DOI: 10.1016/S0040-4039(01)85960-8 |
0.364 |
|
| 1979 |
OVERMAN LE, KNOLL FM. ChemInform Abstract: CATALYZED SIGMATROPIC REARRANGEMENTS. 4. PALLADIUM(II)-CATALYZED REARRANGEMENT OF ALLYLIC ACETATES Chemischer Informationsdienst. 10. DOI: 10.1002/chin.197919143 |
0.311 |
|
| 1978 |
Overman LE, Kakimoto M. Preparation of rearranged allylic isocyanates from the reaction of allylic alkoxides with cyanogen chloride The Journal of Organic Chemistry. 43: 4564-4567. DOI: 10.1021/Jo00418A002 |
0.458 |
|
| 1978 |
Overman LE, Taylor GF, Petty CB, Jessup PJ. trans-1-N-Acylamino-1,3-dienes: preparation from dienoic acids The Journal of Organic Chemistry. 43: 2164-2167. DOI: 10.1021/Jo00405A017 |
0.317 |
|
| 1978 |
Overman LE, Jessup PJ. Synthetic applications of N-acylamino-1,3-dienes. An efficient stereospecific total synthesis of dl-pumiliotoxin C, and a general entry to cis-decahydroquinoline alkaloids Journal of the American Chemical Society. 100: 5179-5185. DOI: 10.1021/Ja00484A046 |
0.412 |
|
| 1978 |
Overman LE, Campbell CB, Knoll FM. Mild procedures for interconverting allylic oxygen functionality. Cyclization-induced [3,3] sigmatropic rearrangement of allylic carbamates Journal of the American Chemical Society. 100: 4822-4834. DOI: 10.1021/Ja00483A032 |
0.332 |
|
| 1978 |
Overman LE, Taylor GF, Houk KN, Domelsmith LN. Diels-Alder reactions between trans-1-N-acylamino-1,3-dienes and methyl acrylate. A correlation between diene photoelectron ionization potentials and reactivity, stereoselectivity, and regioselectivity Journal of the American Chemical Society. 100: 3182-3189. DOI: 10.1021/Ja00478A038 |
0.391 |
|
| 1978 |
Fleming I, Michael JP, Overman LE, Taylor GF. How important is secondary overlap in determining the regioselectivity of Diels-Alder reactions? Tetrahedron Letters. 19: 1313-1314. DOI: 10.1016/0040-4039(78)80116-6 |
0.366 |
|
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