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H. Holden Thorp - Publications

Affiliations: 
2013 Chemistry University of North Carolina, Chapel Hill, Chapel Hill, NC 
 2013-2019 Washington University, Saint Louis, St. Louis, MO 
 2019- Editor in Chief Science magazine 
Area:
Biological Application of Transition Metal Redox Chemistry
Website:
https://www.aaas.org/person/holden-thorp
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124 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Year Citation  Score
2018 Murphy CF, Dongare P, Weatherly SC, Gagliardi CJ, Thorp HH, Meyer TJ. Proton-Coupled Electron Transfer in the Oxidation of Guanosine Monophosphate by Ru(bpy)33+ The Journal of Physical Chemistry C. 122: 24830-24837. DOI: 10.1021/Acs.Jpcc.8B08382  0.812
2015 Gagliardi CJ, Murphy CF, Binstead RA, Thorp HH, Meyer TJ. Concerted electron proton transfer (EPT) in the oxidation of cysteine Journal of Physical Chemistry C. 119: 7028-7038. DOI: 10.1021/Acs.Jpcc.5B00368  0.473
2012 Song N, Gagliardi CJ, Binstead RA, Zhang MT, Thorp H, Meyer TJ. Role of proton-coupled electron transfer in the redox interconversion between benzoquinone and hydroquinone Journal of the American Chemical Society. 134: 18538-18541. PMID 23113818 DOI: 10.1021/Ja308700T  0.5
2011 Gagliardi CJ, Binstead RA, Thorp HH, Meyer TJ. Concerted electron-proton transfer (EPT) in the oxidation of tryptophan with hydroxide as a base. Journal of the American Chemical Society. 133: 19594-7. PMID 22032235 DOI: 10.1021/Ja207379N  0.512
2011 Gagliardi CJ, Jurss JW, Thorp HH, Meyer TJ. Surface activation of electrocatalysis at oxide electrodes. Concerted electron-proton transfer. Inorganic Chemistry. 50: 2076-8. PMID 21302912 DOI: 10.1021/Ic102524F  0.55
2010 Campbell JF, Napier ME, Feldberg SW, Thorp HH. Metal-mediated electrochemical oxidation of DNA-wrapped carbon nanotubes. The Journal of Physical Chemistry. B. 114: 8861-70. PMID 20565119 DOI: 10.1021/Jp101809E  0.466
2010 Holcomb DR, Ropp PA, Theil EC, Thorp HH. Nature of guanine oxidation in RNA via the flash-quench technique versus direct oxidation by a metal oxo complex. Inorganic Chemistry. 49: 786-95. PMID 20038124 DOI: 10.1021/Ic9008619  0.762
2010 Fecenko CJ, Meyer TJ, Thorp HH. Electrocatalytic oxidation of tyrosine by parallel rate-limiting proton transfer and multisite electron-proton transfer (J. Am. Chem. Soc. (2006) 128 (1102011021)) Journal of the American Chemical Society. 132: 5323. DOI: 10.1021/Ja1015266  0.506
2010 SARNESKI JE, MICHOS D, THORP HH, DIDIUK M, POON T, BLEWITT J, BRUDVIG GW, CRABTREE RH. ChemInform Abstract: Alkyl Hydroperoxide Oxidation of Alkanes and Alkenes with a Highly Active Mn Catalyst. Cheminform. 22: no-no. DOI: 10.1002/chin.199152093  0.575
2010 SARNESKI JE, THORP HH, BRUDVIG GW, CRABTREE RH, SCHULTE GK. ChemInform Abstract: Assembly of High-Valent Oxomanganese Clusters in Aqueous Solution. Redox Equilibrium of Water-Stable Mn3O4+ 4 and Mn2O3+ 2 Complexes. Cheminform. 22: no-no. DOI: 10.1002/chin.199102283  0.555
2008 Campbell JF, Tessmer I, Thorp HH, Erie DA. Atomic force microscopy studies of DNA-wrapped carbon nanotube structure and binding to quantum dots. Journal of the American Chemical Society. 130: 10648-55. PMID 18627153 DOI: 10.1021/Ja801720C  0.343
2007 Fecenko CJ, Thorp HH, Meyer TJ. The role of free energy change in coupled electron-proton transfer. Journal of the American Chemical Society. 129: 15098-9. PMID 17999500 DOI: 10.1021/Ja072558D  0.534
2007 Meyer TJ, Huynh MH, Thorp HH. The possible role of proton-coupled electron transfer (PCET) in water oxidation by photosystem II. Angewandte Chemie (International Ed. in English). 46: 5284-304. PMID 17604381 DOI: 10.1002/Anie.200600917  0.504
2007 Sullivan JM, Ropp PA, Thorp HH, Theil EC. In vitro up‐regulation of ferritin expression mediated by small molecules that target mRNA The Faseb Journal. 21. DOI: 10.1096/Fasebj.21.5.A281  0.499
2007 Meyer T, Huynh M, Thorp H. Zur möglichen Rolle des protonengekoppelten Elektronentransfers (PCET) bei der Oxidation von Wasser durch das Photosystem II Angewandte Chemie. 119: 5378-5399. DOI: 10.1002/Ange.200600917  0.412
2006 Fecenko CJ, Meyer TJ, Thorp HH. Electrocatalytic oxidation of tyrosine by parallel rate-limiting proton transfer and multisite electron-proton transfer. Journal of the American Chemical Society. 128: 11020-1. PMID 16925408 DOI: 10.1021/Ja061931Z  0.578
2006 Paul JJ, Kircus SR, Sorrell TN, Ropp PA, Thorp HH. Effects of coordinating metal ions on the mediated inhibition of trypsin by bis(benzimidazoles) and related compounds. Inorganic Chemistry. 45: 5126-35. PMID 16780335 DOI: 10.1021/Ic0516461  0.747
2006 Tibodeau JD, Fox PM, Ropp PA, Theil EC, Thorp HH. The up-regulation of ferritin expression using a small-molecule ligand to the native mRNA. Proceedings of the National Academy of Sciences of the United States of America. 103: 253-7. PMID 16381820 DOI: 10.1073/Pnas.0509744102  0.763
2005 Napier ME, Hull DO, Thorp HH. Electrocatalytic oxidation of DNA-wrapped carbon nanotubes. Journal of the American Chemical Society. 127: 11952-3. PMID 16117529 DOI: 10.1021/Ja054162C  0.792
2004 Holmberg RC, Thorp HH. Electrochemical determination of triple helices: electrocatalytic oxidation of guanine in an intramolecular triplex. Inorganic Chemistry. 43: 5080-5. PMID 15285684 DOI: 10.1021/Ic049895X  0.773
2004 Tibodeau JD, Thorp HH. Probing the solvent accessibility and electron density of adenine: oxidation of 7-deazaadenine in bent DNA and purine doublets. Inorganic Chemistry. 43: 408-10. PMID 14731001 DOI: 10.1021/Ic034989C  0.813
2004 Leone AM, Hull DO, Wang W, Thorp HH, Murray RW. Electrocatalysis in nucleic acid molten salts Journal of Physical Chemistry A. 108: 9787-9793. DOI: 10.1021/Jp048995L  0.804
2003 Gore MR, Szalai VA, Ropp PA, Yang IV, Silverman JS, Thorp HH. Detection of attomole quantities [correction of quantitites] of DNA targets on gold microelectrodes by electrocatalytic nucleobase oxidation. Analytical Chemistry. 75: 6586-92. PMID 14640732 DOI: 10.1021/Ac034918V  0.789
2003 Thorp HH. Reagentless detection of DNA sequences on chemically modified electrodes. Trends in Biotechnology. 21: 522-4. PMID 14624859 DOI: 10.1016/J.Tibtech.2003.10.003  0.317
2003 Holmberg RC, Tierney MT, Ropp PA, Berg EE, Grinstaff MW, Thorp HH. Intramolecular electrocatalysis of 8-oxo-guanine oxidation: secondary structure control of electron transfer in osmium-labeled oligonucleotides. Inorganic Chemistry. 42: 6379-87. PMID 14514313 DOI: 10.1021/Ic030004F  0.798
2003 Benites PJ, Holmberg RC, Rawat DS, Kraft BJ, Klein LJ, Peters DG, Thorp HH, Zaleski JM. Metal-ligand charge-transfer-promoted photoelectronic Bergman cyclization of copper metalloenediynes: photochemical DNA cleavage via C-4' H-atom abstraction. Journal of the American Chemical Society. 125: 6434-46. PMID 12785783 DOI: 10.1021/Ja020939F  0.75
2003 Leone AM, Tibodeau JD, Bull SH, Feldberg SW, Thorp HH, Murray RW. Ion atmosphere relaxation and percolative electron transfer in Co bipyridine DNA molten salts. Journal of the American Chemical Society. 125: 6784-90. PMID 12769589 DOI: 10.1021/Ja0348795  0.81
2003 Holmberg RC, Thorp HH. Digital simulation of catalytic cyclic voltammograms for oxidation of DNA by a heterobimetallic dimer: effects of DNA binding and mass transport. Analytical Chemistry. 75: 1851-60. PMID 12713043 DOI: 10.1021/Ac0204653  0.765
2003 Leone AM, Brennaman MK, Tibodeau JD, Papanikolas JM, Murray RW, Thorp HH. Photoinduced electron transfer in nucleic acid molten salts Journal of Physical Chemistry B. 107: 6469-6473. DOI: 10.1021/Jp022586C  0.79
2003 Weatherly SC, Yang IV, Armistead PA, Thorp HH. Proton-coupled electron transfer in guanine oxidation: Effects of isotope, solvent, and chemical modification Journal of Physical Chemistry B. 107: 372-378. DOI: 10.1021/Jp022085R  0.796
2002 Armistead PM, Thorp HH. Electrochemical detection of gene expression in tumor samples: overexpression of Rak nuclear tyrosine kinase. Bioconjugate Chemistry. 13: 172-6. PMID 11906252 DOI: 10.1021/Bc000129Y  0.615
2002 Szalai VA, Singer MJ, Thorp HH. Site-specific probing of oxidative reactivity and telomerase function using 7,8-dihydro-8-oxoguanine in telomeric DNA. Journal of the American Chemical Society. 124: 1625-31. PMID 11853436 DOI: 10.1021/Ja0119651  0.795
2002 Yang IV, Ropp PA, Thorp HH. Toward electrochemical resolution of two genes on one electrode: using 7-deaza analogues of guanine and adenine to prepare PCR products with differential redox activity. Analytical Chemistry. 74: 347-54. PMID 11811407 DOI: 10.1021/Ac0109063  0.61
2002 Szalai VA, Jayawickamarajah J, Thorp HH. Electrocatalysis of guanine oxidation in polyethylene glycol solutions: The interplay of adsorption and reaction rate Journal of Physical Chemistry B. 106: 709-716. DOI: 10.1021/Jp012362E  0.794
2001 Yang IV, Thorp HH. Modification of indium tin oxide electrodes with repeat polynucleotides: electrochemical detection of trinucleotide repeat expansion. Analytical Chemistry. 73: 5316-22. PMID 11721935 DOI: 10.1021/Ac010062N  0.612
2001 Weatherly SC, Yang IV, Thorp HH. Proton-coupled electron transfer in duplex DNA: driving force dependence and isotope effects on electrocatalytic oxidation of guanine. Journal of the American Chemical Society. 123: 1236-7. PMID 11456681 DOI: 10.1021/Ja003788U  0.804
2001 Leone AM, Weatherly SC, Williams ME, Thorp HH, Murray RW. An ionic liquid form of DNA: redox-active molten salts of nucleic acids. Journal of the American Chemical Society. 123: 218-22. PMID 11456507 DOI: 10.1021/Ja003332C  0.8
2001 Yang IV, Thorp HH. Oxidation of 7-deazaguanine by one-electron and oxo-transfer oxidants: mismatch-dependent electrochemistry and selective strand scission. Inorganic Chemistry. 40: 1690-7. PMID 11261981 DOI: 10.1021/Ic001057P  0.667
2001 Armistead PM, Thorp HH. Oxidation kinetics of guanine in DNA molecules adsorbed onto indium tin oxide electrodes. Analytical Chemistry. 73: 558-64. PMID 11217762 DOI: 10.1021/Ac001286T  0.696
2001 Baik MH, Silverman JS, Yang IV, Ropp PA, Szalai VA, Yang W, Thorp HH. Using density functional theory to design DNA base analogues with low oxidation potentials Journal of Physical Chemistry B. 105: 6437-6444. DOI: 10.1021/Jp010643G  0.804
2000 Thorp HH. CHEMISTRY: Harnessing the Power of Diatomics. Science (New York, N.Y.). 289: 882-3. PMID 17839155 DOI: 10.1126/Science.289.5481.882  0.307
2000 Farrer BT, Thorp HH. Redox pathways in DNA oxidation: kinetic studies of guanine and sugar oxidation by para-substituted derivatives of oxoruthenium(IV). Inorganic Chemistry. 39: 44-9. PMID 11229031 DOI: 10.1021/Ic990833U  0.475
2000 Yang IV, Thorp HH. Kinetics of metal-mediated one-electron oxidation of guanine in polymeric DNA and in oligonucleotides containing trinucleotide repeat sequences. Inorganic Chemistry. 39: 4969-76. PMID 11196978 DOI: 10.1021/Ic000607G  0.651
2000 Suing AL, Dewan CR, White PS, Thorp HH. Ethanol oxidation by imidorhenium(V) complexes: formation of amidorhenium(III) complexes. Inorganic Chemistry. 39: 6080-5. PMID 11151507 DOI: 10.1021/Ic0007299  0.321
2000 Armistead PM, Thorp HH. Modification of indium tin oxide electrodes with nucleic acids: detection of attomole quantities of immobilized DNA by electrocatalysis Analytical Chemistry. 72: 3764-70. PMID 10959961 DOI: 10.1021/Ac000051E  0.694
2000 Thorp HH. The importance of being r: greater oxidative stability of RNA compared with DNA. Chemistry & Biology. 7: R33-6. PMID 10662699 DOI: 10.1016/S1074-5521(00)00080-6  0.346
2000 Szalai VA, Thorp HH. Electrocatalysis of guanine electron transfer: New insights from submillimeter carbon electrodes Journal of Physical Chemistry B. 104: 6851-6859. DOI: 10.1021/Jp000912N  0.801
2000 Sistare MF, Codden SJ, Heimlich G, Thorp HH. Effects of base stacking on guanine electron transfer: Rate constants for G and GG sequences of oligonucleotides from catalytic electrochemistry Journal of the American Chemical Society. 122: 4742-4749. DOI: 10.1021/Ja993240R  0.358
2000 Farrer BT, Pickett JS, Thorp HH. Hydride transfer in oxidation of nucleic acid sugars: Electronic effects of 2'-substituents on activation of the 1'-C-H bond by oxoruthenium(IV) Journal of the American Chemical Society. 122: 549-553. DOI: 10.1021/Ja991967+  0.405
2000 Szalai VA, Thorp HH. Electron transfer in tetrads: Adjacent guanines are not hole traps in G quartets [9] Journal of the American Chemical Society. 122: 4524-4525. DOI: 10.1021/Ja0001355  0.771
1999 Ontko AC, Armistead PM, Kircus SR, Thorp HH. Electrochemical Detection of Single-Stranded DNA Using Polymer-Modified Electrodes. Inorganic Chemistry. 38: 1842-1846. PMID 11670956 DOI: 10.1021/Ic981211W  0.788
1999 Ropp PA, Thorp HH. Site-selective electron transfer from purines to electrocatalysts: voltammetric detection of a biologically relevant deletion in hybridized DNA duplexes. Chemistry & Biology. 6: 599-605. PMID 10467130 DOI: 10.1016/S1074-5521(99)80111-2  0.441
1999 Napier ME, Thorp HH. Electrocatalytic Oxidation of Nucleic Acids at Electrodes Modified with Nylon and Nitrocellulose Membranes Journal of Fluorescence. 9: 181-186. DOI: 10.1023/A:1022599432000  0.475
1999 Sistare MF, Holmberg RC, Thorp HH. Electrochemical Studies of Polynucleotide Binding and Oxidation by Metal Complexes:  Effects of Scan Rate, Concentration, and Sequence The Journal of Physical Chemistry B. 103: 10718-10728. DOI: 10.1021/Jp992940F  0.775
1999 Farrer BT, Thorp HH. Driving Force and Isotope Dependence of the Kinetics of Proton-Coupled Electron Transfer in Oxoruthenium(IV) Polypyridyl Complexes Inorganic Chemistry. 38: 2497-2502. DOI: 10.1021/Ic9902323  0.392
1998 Ciftan SA, Theil EC, Thorp HH. Oxidation of guanines in the iron-responsive element RNA: similar structures from chemical modification and recent NMR studies. Chemistry & Biology. 5: 679-87. PMID 9862796 DOI: 10.1016/S1074-5521(98)90661-5  0.331
1998 Carter PJ, Breiner KM, Thorp HH. Effects of secondary structure on DNA and RNA cleavage by diplatinum(II). Biochemistry. 37: 13736-43. PMID 9753462 DOI: 10.1021/Bi981479Z  0.427
1998 Frohnapfel DS, Woodworth BE, Thorp HH, Templeton JL. Variable electronic coupling through hydrocarbon spacers bridging metal-carbon triple bonds Journal of Physical Chemistry A. 102: 5665-5669. DOI: 10.1021/Jp980382J  0.369
1998 Ciftan SA, Thorp HH. Conformation-dependent cleavage of hairpin and triplex nucleic acids by a temperature-insensitive photonuclease Journal of the American Chemical Society. 120: 9995-10000. DOI: 10.1021/Ja981166R  0.334
1998 Carter PJ, Cheng CC, Thorp HH. Oxidation of DNA and RNA by oxoruthenium(IV) metallointercalators: Visualizing the recognition properties of dipyridophenazine by high-resolution electrophoresis Journal of the American Chemical Society. 120: 632-642. DOI: 10.1021/Ja9729589  0.347
1998 Ciftan SA, Hondros DP, Thorp HH. Quenching of Guanine Oxidation by Oxoruthenium(IV):  Effects of Divalent Cations on Chemical Nuclease Studies Inorganic Chemistry. 37: 1598-1601. DOI: 10.1021/Ic9711372  0.408
1998 Thorp HH. Cutting out the middleman: DNA biosensors based on electrochemical oxidation Trends in Biotechnology. 16: 117-121. DOI: 10.1016/S0167-7799(97)01162-1  0.37
1998 Smith SR, Thorp HH. Application of the electrocatalytic reduction of nitric oxide mediated by ferrioxamine B to the determination of nitric oxide concentrations in solution Inorganica Chimica Acta. 273: 316-319. DOI: 10.1016/S0020-1693(97)06062-3  0.386
1998 Kim J, Sistare MF, Carter PJ, Thorp HH. Electron and hydrogen transfer reactions of nucleotides: From Stern-Volmer quenching to nucleoprotein structure Coordination Chemistry Reviews. 171: 341-349. DOI: 10.1016/S0010-8545(98)90051-0  0.4
1997 Welch TW, Ciftan SA, White PS, Thorp HH. Electron-Rich Oxoruthenium(IV) Cleavage Agents: A Zero-Order Rate Law for DNA Catalysis. Inorganic Chemistry. 36: 4812-4821. PMID 11670161 DOI: 10.1021/Ic9703944  0.476
1997 Napier ME, Loomis CR, Sistare MF, Kim J, Eckhardt AE, Thorp HH. Probing biomolecule recognition with electron transfer: electrochemical sensors for DNA hybridization. Bioconjugate Chemistry. 8: 906-13. PMID 9404665 DOI: 10.1021/Bc9701149  0.402
1997 Carter PJ, Ciftan SA, Sistare MF, Thorp HH. Perfect strangers: Inorganic photochemistry and nucleic acids Journal of Chemical Education. 74: 641-645. DOI: 10.1021/Ed074P641  0.344
1997 Kim J, Thorp HH, Kumar S, Roberts RJ. Effect of base flipping on guanine-metal electron transfer Journal of Inorganic Biochemistry. 67: 368. DOI: 10.1016/S0162-0134(97)80235-8  0.35
1996 Carter PJ, Cheng CC, Thorp HH. Oxidation of DNA Hairpins by Oxoruthenium(IV): Effects of Sterics and Secondary Structure. Inorganic Chemistry. 35: 3348-3354. PMID 11666537 DOI: 10.1021/Ic9515517  0.468
1996 Kazmierski WM, Wolberg G, Wilson JG, Smith SR, Williams DS, Thorp HH, Molina L. Iron chelates bind nitric oxide and decrease mortality in an experimental model of septic shock. Proceedings of the National Academy of Sciences of the United States of America. 93: 9138-41. PMID 8799167 DOI: 10.1073/Pnas.93.17.9138  0.315
1996 Johnston DH, Welch TW, Thorp HH. Electrochemically activated nucleic acid oxidation. Metal Ions in Biological Systems. 33: 297-324. PMID 8742847  0.514
1996 Johnston DH, Thorp HH. Cyclic voltammetry studies of polynucleotide binding and oxidation by metal complexes: Homogeneous electron-transfer kinetics Journal of Physical Chemistry. 100: 13837-13843. DOI: 10.1021/Jp960252F  0.619
1996 Welch TW, Thorp HH. Distribution of metal complexes bound to DNA determined by normal pulse voltammetry Journal of Physical Chemistry. 100: 13829-13836. DOI: 10.1021/Jp960251N  0.414
1996 Thorp HH, McKenzie RA, Lin P, Walden WE, Theil EC. Cleavage of Functionally Relevant Sites in Ferritin mRNA by Oxidizing Metal Complexes Inorganic Chemistry. 35: 2773-2779. DOI: 10.1021/Ic951094U  0.338
1996 Goll JG, Thorp HH. Oxidation of DNA by trans-dioxoruthenium(VI) complexes: Self-inhibition of DNA cleavage by metal complexes Inorganica Chimica Acta. 242: 219-223. DOI: 10.1016/0020-1693(95)04870-7  0.444
1995 Neyhart GA, Cheng CC, Thorp HH. Kinetics and Mechanism of the Oxidation of Sugars and Nucleotides by Oxoruthenium(IV): Model Studies for Predicting Cleavage Patterns in Polymeric DNA and RNA. Journal of the American Chemical Society. 117: 1463-1471. PMID 28186731 DOI: 10.1021/Ja00110A001  0.382
1995 Breiner KM, Daugherty MA, Oas TG, Thorp HH. An anionic diplatinum DNA photocleavage agent: Chemical mechanism and footprinting of λ repressor Journal of the American Chemical Society. 117: 11673-11679. DOI: 10.1021/Ja00152A007  0.332
1995 Liu W, Thorp HH. Photoinduced proton transfer between transdioxorhenium(V) and metal hydrides: A new method for quantitating kinetic acidities Journal of the American Chemical Society. 117: 9822-9825. DOI: 10.1021/Ja00144A006  0.317
1995 Johnston DH, Glasgow KC, Thorp HH. Electrochemical measurement of the solvent accessibility of nucleobases using electron transfer between DNA and metal complexes Journal of the American Chemical Society. 117: 8933-8938. DOI: 10.1021/Ja00140A006  0.621
1995 Cheng CC, Goll JG, Neyhart GA, Welch TW, Singh P, Thorp HH. Relative rates and potentials of competing redox processes during DNA cleavage: Oxidation mechanisms and sequence-specific catalysis of the self-inactivation of oxometal oxidants by DNA Journal of the American Chemical Society. 117: 2970-2980. DOI: 10.1021/Ja00116A002  0.429
1995 Thorp HH. Electron-, Energy-, and Atom-Transfer Reactions Between Metal Complexes and Dna Advances in Inorganic Chemistry. 43: 127-177. DOI: 10.1016/S0898-8838(08)60117-8  0.439
1995 Smith SR, Thorp HH. Catalytic reduction of nitric oxide by ferrioxamine B: Transition metal therapy for septic shock Journal of Inorganic Biochemistry. 59: 208. DOI: 10.1016/0162-0134(95)97314-G  0.326
1995 Grover N, Ciftan SA, Thorp HH. Mg2+-activated double-stranded DNA cleavage by [(bpy)2(OH2)RuIIIORuIII(H2O) (bpy)2]4+ Inorganica Chimica Acta. 240: 335-338. DOI: 10.1016/0020-1693(95)04550-3  0.435
1994 Johnston DH, Cheng C, Campbell KJ, Thorp HH. Trans-Dioxorhenium(V)-Mediated Electrocatalytic Oxidation of DNA at Indium Tin-Oxide Electrodes: Voltammetric Detection of DNA Cleavage in Solution Inorganic Chemistry. 33: 6388-6390. DOI: 10.1021/Ic00104A058  0.654
1994 Grover N, Welch TW, Fairley TA, Cory M, Thorp HH. Covalent binding of aquaruthenium complexes to DNA Inorganic Chemistry®. 33: 3544-3548. DOI: 10.1021/Ic00094A018  0.362
1994 Kalsbeck WA, Thorp HH. Role of the buffer cation in determining DNA binding constants for metal complexes Inorganic Chemistry. 33: 3427-3429. DOI: 10.1021/Ic00093A036  0.386
1994 Liu W, Thorp HH. Effect of ancillary ligands on the proton-transfer reactivity of the excited state of trans-dioxorhenium(V) Inorganic Chemistry. 33: 1026-1031. DOI: 10.1021/Ic00084A010  0.349
1993 Goll JG, Liu W, Thorp HH. Excited-state quenching through large intrinsic barriers: Proton-transfer reactions of metal hydrides Journal of the American Chemical Society. 115: 11048-11049. DOI: 10.1021/Ja00076A096  0.302
1993 Welch TW, Neyhart GA, Goll JG, Ciftan SA, Thorp HH. Thymidine-specific depyrimidination of DNA by oxopolypyridylruthenium(IV) complexes Journal of the American Chemical Society. 115: 9311-9312. DOI: 10.1021/Ja00073A066  0.381
1993 Kalsbeck WA, Thorp HH. Determining binding constants of metal complexes to DNA by quenching of the emission of Pt2(pop)4 4- (pop = P2O5H2 2-) Journal of the American Chemical Society. 115: 7146-7151. DOI: 10.1021/Ja00069A012  0.384
1993 Neyhart GA, Grover N, Smith SR, Kalsbeck WA, Fairley TA, Cory M, Thorp HH. Binding and kinetics studies of oxidation of DNA by oxoruthenium(IV) Journal of the American Chemical Society. 115: 4423-4428. DOI: 10.1021/Ja00064A001  0.394
1993 Liu W, Thorp HH. Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes. 2. Refined distances and other enzymes Inorganic Chemistry. 32: 4102-4105. DOI: 10.1021/Ic00071A023  0.33
1993 Grover N, Thorp H. Mg2+-activated cleavage of DNA by (bpy)2(OH2)RuORu(OH2)(bpy)24+ Journal of Inorganic Biochemistry. 51: 544. DOI: 10.1016/0162-0134(93)85570-X  0.334
1993 Thorp H. Mechanistic and kinetic studies of DNA cleavage by oxoruthenium(IV) Journal of Inorganic Biochemistry. 51: 518. DOI: 10.1016/0162-0134(93)85544-I  0.369
1993 Thorp HH. New mechanisms in DNA cleavage by metal complexes Journal of Inorganic and Organometallic Polymers. 3: 41-57. DOI: 10.1007/Bf00696752  0.416
1992 Sarneski JE, Thorp HH, Brudvig GW, Crabtree RH, Schulte GK. Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes. [Erratum to document cited in CA113(18):161042g] Journal of the American Chemical Society. 114: 5907-5907. DOI: 10.1021/Ja00040A092  0.594
1992 Grover N, Gupta N, Thorp HH. Stereoselective covalent binding of aquaruthenium(II) complexes to DNA Journal of the American Chemical Society. 114: 3390-3393. DOI: 10.1021/Ja00035A034  0.405
1992 Bruce MRM, Megehee E, Sullivan BP, Thorp HH, O'Toole TR, Downard A, Pugh JR, Meyer TJ. Electrocatalytic reduction of carbon dioxide based on 2,2′-bipyridyl complexes of osmium Inorganic Chemistry. 31: 4864-4873. DOI: 10.1021/Ic00049A027  0.453
1992 Manchanda R, Thorp HH, Brudvig GW, Crabtree RH. An unusual example of multiple proton-coupled electron transfers in a high-valent oxomanganese dimer, [(phen)2MnIII(O)2MnIV(phen)2](ClO4)3 (phen = 1,10 phenanthroline) Inorganic Chemistry. 31: 4040-4041. DOI: 10.1021/Ic00046A007  0.626
1992 Grover N, Gupta N, Singh P, Thorp HH. Studies of electrocatalytic DNA cleavage by oxoruthenium(IV). X-ray crystal structure of [Ru(tpy)(tmen)OH2](ClO4)2 (tmen = N,N,N',N'-tetramethylethylenediamine, tpy = 2,2',2''-terpyridine) Inorganic Chemistry. 31: 2014-2020. DOI: 10.1021/Ic00037A008  0.358
1992 Efros LL, Thorp HH, Brudvig GW, Crabtree RH. Toward a functional model of hydrogenase: Electrocatalytic reduction of protons to dihydrogen by a nickel macrocyclic complex Inorganic Chemistry. 31: 1722-1724. DOI: 10.1021/Ic00035A039  0.615
1992 Thorp HH. Bond valence sum analysis of metal-ligand bond lengths in metalloenzymes and model complexes Inorganic Chemistry. 31: 1585-1588. DOI: 10.1021/Ic00035A012  0.32
1992 Jones MW, Gupta N, Schepartz A, Thorp HH. Binding of alkali-metal cations by self-assembling ionophore complexes of nickel(II) Inorganic Chemistry. 31: 1308-1310. DOI: 10.1021/Ic00033A036  0.311
1992 Gupta N, Grover N, Neyhart GA, Liang W, Singh P, Thorp HH. [RuO(dppz)(tpy)]2+: A DNA cleavage agent with high DNA affinity Angewandte Chemie (International Edition in English). 31: 1048-1050. DOI: 10.1002/Anie.199210481  0.342
1991 Thorp HH, Gray HB. PHOTOPHYSICS OF DIOXORHENIUM(V) IN NAFION Photochemistry and Photobiology. 54: 609-612. DOI: 10.1111/J.1751-1097.1991.Tb02063.X  0.413
1991 Grover N, Thorp HH. Efficient electrocatalytic and stoichiometric oxidative cleavage of DNA by oxoruthenium(IV) Journal of the American Chemical Society. 113: 7030-7031. DOI: 10.1021/Ja00018A048  0.432
1991 Brewer JC, Thorp HH, Slagle KM, Brudvig GW, Gray HB. Electronic structure of trans-dioxorhenium(VI) Journal of the American Chemical Society. 113: 3171-3173. DOI: 10.1021/Ja00008A055  0.642
1991 Sarneski JE, Didiuk M, Thorp HH, Crabtree RH, Brudvig GW, Faller JW, Schulte GK. A high-valent oxomanganese dimer containing bridging and terminal inorganic phosphate ligands Inorganic Chemistry. 30: 2833-2835. DOI: 10.1021/Ic00014A002  0.584
1991 Thorp HH, Sarneski JE, Kulawiec RJ, Brudvig GW, Crabtree RH, Papaefthymiou GC. Physical properties of a manganese tetramer with all-oxygen coordination Inorganic Chemistry. 30: 1153-1155. DOI: 10.1021/Ic00005A053  0.554
1991 Manchanda R, Thorp HH, Brudvig GW, Crabtree RH. Proton-coupled electron transfer in high-valent oxomanganese dimers: Role of the ancillary ligands Inorganic Chemistry. 30: 494-497. DOI: 10.1021/Ic00003A028  0.643
1991 Brudvig GW, Thorp HH, Crabtree RH. Probing the mechanism of water oxidation in photosystem II Accounts of Chemical Research. 24: 311-316. DOI: 10.1021/Ar00010A005  0.625
1991 Grover N, Thorp H. Efficient oxidative cleavage of DNA by oxoruthenium(IV) Journal of Inorganic Biochemistry. 43: 444. DOI: 10.1016/0162-0134(91)84426-A  0.424
1991 Sarneski JE, Didiuk M, Thorp H, Crabtree RH, Brudvig GW, Faller J, Schulte GK. The chemistry of high-valent oxomanganese clusters in aqueous solution: A (IV,IV) dimer containing bridging and terminal phosphate ligands Journal of Inorganic Biochemistry. 43: 372. DOI: 10.1016/0162-0134(91)84358-G  0.588
1991 Kalsbeck WA, Thorp H, Brudvig GW. Temperature-dependent cyclic voltammetry of oxo-bridged dimers of relevance to photosynthetic water oxidation Journal of Electroanalytical Chemistry and Interfacial Electrochemistry. 314: 335-343. DOI: 10.1016/0022-0728(91)85448-X  0.621
1991 Kalsbeck WA, Grover N, Thorp HH. Photolytic Cleavage of DNA by [Pt2(P2O5H2)4]4− Angewandte Chemie. 30: 1517-1518. DOI: 10.1002/Anie.199115171  0.328
1991 Kalsbeck WA, Grover N, Thorp HH. Photolytische DNA-Spaltung mit [Pt2(P2O5H2)4]4− Angewandte Chemie. 103: 1525-1527. DOI: 10.1002/Ange.19911031128  0.321
1990 Sarneski JE, Thorp HH, Brudvig GW, Crabtree RH, Schulte GK. Assembly of high-valent oxomanganese clusters in aqueous solution. Redox equilibrium of water-stable Mn3O44+ and Mn2O23+ complexes Journal of the American Chemical Society. 112: 7255-7260. DOI: 10.1021/Ja00176A027  0.581
1990 Thorp HH, Brudvig GW, Bowden EF. Proton-coupled electron transfer in[(bpy)2Mn(O)2Mn(bpy)2]3+. Role of the electrode surface Journal of Electroanalytical Chemistry. 290: 293-301. DOI: 10.1016/0022-0728(90)87440-U  0.612
1990 THORP HH, SARNESKI JE, BRUDVIG GW, CRABTREE RH. ChemInform Abstract: Proton-Coupled Electron Transfer in ((bpy)2Mn(O)2Mn(bpy)2)3+. Cheminform. 21. DOI: 10.1002/chin.199013057  0.585
1989 Thorp HH, Sarneski JE, Brudvig GW, Crabtree RH. Proton-coupled electron transfer in manganese complex [(bpy)2Mn(O)2Mn(bpy)2]3+ Journal of the American Chemical Society. 111: 9249-9250. DOI: 10.1021/Ja00208A029  0.637
1989 Thorp HH, Kumar CV, Turro NJ, Gray HB. Emission properties of dioxorhenium(V) complexes in aqueous solutions of anionic and nonionic surfactants: a sensitive probe of hydrophobic binding regions Journal of the American Chemical Society. 111: 4364-4368. DOI: 10.1021/Ja00194A032  0.414
1989 Thorp HH, Van Houten J, Gray HB. Excited-state properties of dioxorhenium(V). Generation and reactivity of dioxorhenium(VI) Inorganic Chemistry. 28: 889-892. DOI: 10.1021/Ic00304A017  0.409
1989 Thorp H, Kulawiec R, Brudvig G, Crabtree R. Modeling the oxygen evolving complex of photosystem II. Redox chemistry and ligand binding of biologically relevant manganese tetramers Journal of Inorganic Biochemistry. 36: 226. DOI: 10.1016/0162-0134(89)84235-7  0.613
1988 Bruce MRM, Megehee E, Sullivan BP, Thorp H, O'Toole TR, Downard A, Meyer TJ. Electrocatalytic reduction of CO2 by associative activation Organometallics. 7: 238-240. DOI: 10.1021/Om00091A039  0.425
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